911402

(CyPAd-DalPhos)NiCl(otol)

≥95%

• Synonyma: 8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
• Empirický vzorec (Hillův zápis): C₃₅H₄₉ClNiO₃P₂
• Číslo CAS: 2115838-60-1
• Molekulová hmotnost: 673.86
• UNSPSC Code: 12352200
• NACRES: NA.22

Vlastnosti

• assay: ≥95%
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• mp: 193-197 °C

Popis

Application

(CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp²)-O coupling and N-arylation reactions.

Other Notes

Technology Spotlight: DalPhos ligands

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

Bezpečnostní informace

• pictograms: GHS08,GHS07,GHS09
• signalword: Danger
• hcodes: H302 + H312 + H332,H341,H351,H372,H410
• pcodes: P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation
• target_organs: Respiratory Tract,Skin
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable