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746746

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

Synonyma:

1.0 M LiPF6 EC/DEC=50/50 (v/v)

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Vybrat velikost

746746-25ML
2 340,00 Kč
100 ML
4 420,00 Kč
500 ML
15 400,00 Kč

2 340,00 Kč


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Vyžádat hromadnou objednávku

Vybrat velikost

Změnit zobrazení
746746-25ML
2 340,00 Kč
100 ML
4 420,00 Kč
500 ML
15 400,00 Kč

About This Item

Lineární vzorec:
LiPF6
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

2 340,00 Kč


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grade

battery grade

Quality Level

form

solution

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

(1.0 M LiPF6 in EC/DEC)

impurities

<15 ppm H2O
<50 ppm HF

color

APHA: <50

bp

130 °C

density

1.26 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

cation traces

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

application(s)

battery manufacturing

greener alternative category

SMILES string

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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General description

Lithium hexafluorophosphate solution in ethylene carbonate and diethyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiPF6 EC/DMC is widely used as an electrolyte that is thermally stable in solvents. It can be mainly used in the fabrication of lithium-ion batteries.[5][6][7]
Liquid electrolyte solutions play a key role in lithium ion batteries (LIB) acting as carrier of lithium ions between the cathode and anode. High purity and battery grade electrolyte solutions are thus crucial for lithium ion battery performance. The most common LIB electrolytes are derived from solutions of lithium salt, such as LiPF6 in non-aqueous solvents, example alkyl carbonates or solvent blend. The choice of the electrolyte solution is dependent on both the operating conditions like temperature and the nature of the electrode material in the LIB. The performance of the electrolyte solutions can be further modified with appropriate additives.
The ready-to-use electrolyte solutions are available in different solvent blends and can support a wide variety of lithium ion battery applications. These solutions are high purity and battery grade thus making them also suitable as standards in LIB research. Customized formulations can be made by inter-mixing the electrolyte solutions or by mixing appropriate of additives.

Other Notes

Handling instructions:
  • Do not use with glass equipment
  • All work should be done very quickly under dry air to prevent electrolytes from water uptake and solvent vaporization.

Legal Information

Product of MU Ionic Solutions Corp

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT RE 2 Oral

target_organs

Bone,Teeth, Kidney

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

86.0 °F

flash_point_c

30 °C


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Osvědčení o analýze (COA)

Lot/Batch Number

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Již tento produkt vlastníte?

Dokumenty související s produkty, které jste v minulosti zakoupili, byly za účelem usnadnění shromážděny ve vaší Knihovně dokumentů.

Navštívit knihovnu dokumentů

Comparison of the thermal stability of lithiated graphite in LiBOB EC/DEC and in LiPF6 EC/DEC
Jiang J and Dahn JR
Electrochemical and Solid-State Letters, 6(9), A180-A180 (2003)
Reactivity of charged LiVPO4F with 1 M LiPF6 EC: DEC electrolyte at high temperature as studied by accelerating rate calorimetry
Zhou F, et al.
Electrochemical Communications, 11(3), 589-591 (2009)
Lucht, B. L.;
Energy Production and Storage, 333-333 (2010)
Visualization of electrode-electrolyte interfaces in LiPF6/EC/DEC electrolyte for lithium ion batteries via in situ TEM
Zeng Z, et al.
Nano Letters, 14(4), 1745-1750 (2014)
Lex-Balducci, A.;
Lithium-Ion Batteries, 147-147 (2012)

Sortimentní položky

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

Zobrazit všechny

Související obsah

Baterie, palivové články a superkondenzátory jsou založeny na elektrochemické výrobě energie. Pochopte jejich fungování a rozdělení přenosu elektronů a iontů.

Batteries, fuel cells, and supercapacitors rely on electrochemical energy production. Understand their operation and electron/ion transport separation.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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