373710
Molybdenum(VI) dichloride dioxide
Synonyma:
Dichlorodioxomolybdenum
Přihlásitk zobrazení cen stanovených pro organizaci a smluvních cen
About This Item
Lineární vzorec:
MoO2Cl2
Číslo CAS:
Molekulová hmotnost:
198.84
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
grade:
for analytical purposes
form:
flakes
Doporučené produkty
grade
for analytical purposes
form
flakes
concentration
34.4-36.9% chloride (silver nitrate titration)
density
3.31 g/mL at 25 °C (lit.)
application(s)
battery manufacturing
SMILES string
Cl[Mo](Cl)(=O)=O
InChI
1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2
InChI key
JCFNAADCQWXIJD-UHFFFAOYSA-L
General description
Molybdenum(VI) dichloride dioxide is an oxo-halide of molybdenum widely used as a catalyst for various organic transformations. It is an oxo-transfer catalyst that has the ability to promote oxidation as well as reduction reactions. It can also be used as a chemical vapor deposition(CVD) precursor to synthesize various Mo-based nanomaterials.
Application
Molybdenum(VI) dichloride dioxide can be used as a catalyst:
- For thioacetalization of heterocyclic, aromatic, and aliphatic compounds.
- To synthesize mono-, di-, tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates.
- For stereospecific deoxygenation of epoxides to alkenes.
- For the synthesis of dihydropyrimidinone/thione and polyhydroquinoline derivatives via a Biginelli and Hantzsch reaction.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Vyberte jednu z posledních verzí:
Již tento produkt vlastníte?
Dokumenty související s produkty, které jste v minulosti zakoupili, byly za účelem usnadnění shromážděny ve vaší Knihovně dokumentů.
Zákazníci si také prohlíželi
Interplay between size and crystal structure of molybdenum dioxide nanoparticles?synthesis, growth mechanism, and electrochemical performance
Dorota Koziej, et al.
Small, 7, 377-387 (2011)
Molybdenum pentachloride (MoCl5) or molybdenum dichloride dioxide (MoO2Cl2): advanced catalysts for thioacetalization of heterocyclic, aromatic and aliphatic compounds
Shyamaprosad Goswami and Annada C. Maity
Tetrahedron Letters, 49, 3092-3096 (2008)
Mild and high-yielding molybdenum (VI) dichloride dioxide-catalyzed formation of mono-, di-, tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates
Christian Stock, et al.
advanced synthesis and catalysis, 354, 2309-2330 (2012)
MoO2Cl2 catalyzed efficient synthesis of functionalized 3,4-dihydropyrimidin-2 (1 H)-ones/thiones and polyhydroquinolines: recyclability, fluorescence and biological studies
Sravanthi Devi Guggilapu, et al.
Journal of Chemistry, 40, 838-843 (2016)
Molybdenum-Catalyzed Stereospecific Deoxygenation of Epoxides to Alkenes
Sobi Asako, et al.
advanced synthesis and catalysis, 358, 3966-3970 (2016)
Náš tým vědeckých pracovníků má zkušenosti ve všech oblastech výzkumu, včetně přírodních věd, materiálových věd, chemické syntézy, chromatografie, analytiky a mnoha dalších..
Obraťte se na technický servis.