23070

(1-Chloroethyl)trimethylsilane

technical, ≥90% (GC)

• Empirický vzorec (Hillův zápis): C₅H₁₃ClSi
• Číslo CAS: 7787-87-3
• Molekulová hmotnost: 136.70
• Beilstein/REAXYS Number: 1732094
• EC Number: 232-135-8
• MDL number: MFCD00042611
• UNSPSC Code: 12352100
• PubChem Substance ID: 57648018
• NACRES: NA.22

Vlastnosti

• grade: technical
• assay: ≥90% (GC)
• form: liquid
• refractive index: n20/D 1.422
• bp: 116 °C (lit.)
• density: 0.864 g/mL at 20 °C (lit.)
• SMILES string: CC(Cl)[Si](C)(C)C
• InChI: 1S/C5H13ClSi/c1-5(6)7(2,3)4/h5H,1-4H3
• InChI key: UWJVDEZZIPJQRF-UHFFFAOYSA-N

Popis

Other Notes

Treating this chlorosilane with sec-BuLi gives 1-chloro-1-trimethylsilylethyl lithium which reacts with aldehydes and ketones to form methyl ketones via an intermediate α,β-epoxysilane.; Used in an efficient synthesis of R(+)-frontalin; The Grignard reagent is useful for many reactions

Bezpečnostní informace

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H315,H319,H335
• pcodes: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 68.0 °F
• flash_point_c: 20 °C
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter