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Merck

28612

Sigma-Aldrich

Trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl)phosphinate

≥90.0%

Sinónimos:

Tetradecyltrihexylphosphonium bis(2,4,4-trimethylpentyl)phosphinate

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About This Item

Fórmula empírica (notación de Hill):
C48H102O2P2
Número de CAS:
Peso molecular:
773.27
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥90.0%

impurities

≤1.0% water

density

0.895 g/mL at 20 °C (lit.)

functional group

phosphine

SMILES string

CC(CC(C)(C)C)CP([O-])(=O)CC(C)CC(C)(C)C.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C32H68P.C16H35O2P/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;1-13(9-15(3,4)5)11-19(17,18)12-14(2)10-16(6,7)8/h5-32H2,1-4H3;13-14H,9-12H2,1-8H3,(H,17,18)/q+1;/p-1

InChI key

ZKQLVOZSJHOZBL-UHFFFAOYSA-M

General description

Trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl)phosphinate is a phosphonium-based ionic liquid. It can be prepared by reacting trihexyl(tetradecyl)-phosphonium chloride with bis(2,4,4-trimethylpentyl)phosphinic acid in the presence of a base.
http://www.sigmaaldrich.com/dam/sigma-aldrich/docs/Aldrich/Acta/al_acta_37_1.pdf

Application

It can be used as an extractant for the removal of dibenzothiophene from liquid fuels via extractive desulfurization (EDS).

Features and Benefits

Phosphonium-based ionic liquid possess interesting properties such as:
  • Liquid at room temperature or melting at T <100 °C
  • High thermal stability
  • Immiscible with water
  • Soluble in organic solvents (however, when an excess of water is added to the system, three liquid phases are formed)
  • Stable under basic conditions

Other Notes

A phosphonium phosphinate for use as a polar solvent

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Visite la Librería de documentos

Phosphonium ionic liquids as new, reactive extractants of lactic acid
Martak, J., and S. Schlosser
Chemical Papers, 60.5, 395-398 (2006)
Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids
Cserjesi, Petra, Nandor Nemestothy, and Katalin Belafi-Bako
Journal of Membrane Science, 349.1, 6-11 (2010)
Synthesis, characterization, and application of novel trihexyl tetradecyl phosphonium bis(2,4,4-trimethylpentyl)phosphinate for extractive desulfurization of liquid fuel.
Dharaskar SA, et al.
Fuel Processing Technology, 123, 1-10 (2014)
New epoxy systems based on ionic liquid
Silva, Adriana A., et al.
Polymer, 54.8, 2123-2129 (2013)
An investigation of a phosphinate-based ionic liquid for corrosion protection of magnesium alloy AZ31
Howlett, Patrick C., et al.
Australian Journal of Chemistry, 60.1, 43-46 (2007)

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