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695017

Sigma-Aldrich

Ácido fosfórico

ACS reagent, ≥85 wt. % in H2O

Sinónimos:

Ácido ortofosfórico

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About This Item

Fórmula lineal:
H3PO4
Número de CAS:
7664-38-2
Peso molecular:
98.00
Beilstein/REAXYS Number:
1921286
EC Number:
231-633-2
MDL number:
MFCD00011340
UNSPSC Code:
12352106
PubChem Substance ID:
329761708
NACRES:
NA.21
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grade

ACS reagent

Quality Level

200

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

assay

≥85% H3PO4 basis (by NaOH, titration)

form

liquid

concentration

≥85 wt. % in H2O

technique(s)

NMR: suitable

impurities

reducing substances, passes test
≤0.001% volatile acids (as CH3COOH)

color

APHA: ≤10

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤3 ppm
nitrate (NO3-): ≤5 ppm
sulfate (SO42-): ≤0.003%

cation traces

As: ≤1 ppm
Ca: ≤0.002%
Fe: ≤0.003%
K: ≤0.005%
Mg: ≤0.02%
Mn: ≤0.5 ppm
Na: ≤0.025%
Sb: ≤0.002%
heavy metals: ≤0.001% (by ICP)

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

Gene Information

human ... SRC(6714)

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General description

Phosphoric acid (H3PO4) is useful in industry for treating the metal surfaces to obtain better adhesion of paint and resin coatings.[1]

Application

Phosphoric acid may be employed as standard for the determination of phosphorus-31 nuclear magnetic resonance (31P NMR) chemical shifts of the common phospholipids.[2] It may be employed in the following studies:
  • As external standard for the analysis of lipid composition of human white matter by 31P NMR spectroscopy.[3]
  • As external standard during the acid-labile phosphorylation of histone H4 by 31P NMR spectroscopy.[4]
  • As reference standard to investigate the surface species present on silica/alumina-supported sodium phosphates by pre- and postreaction MAS31P-NMR and FTIR spectroscopies.[5]
  • As catalyst in the vapor-phase Fries rearrangement of phenylacetate at 623K over a series of surface modified and unmodified ZSM-5.[6]

Other Notes

El ácido fosfórico concentrado es aproximadamente H3PO4 (acuoso) al 85%.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCW6813
MKCX1200
MKCW3676
MKCV8021
MKCW0059

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Phosphoric acid solution NMR reference standard, 85% in D2O (99.9 atom % D), NMR tube size 4.2 mm × 8 in. , WGS-5BL Coaxial NMR tube

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93752

Phosphoric acid solution

A simple method of increasing the adhesion of acrylic filling materials to enamel surfaces.
Buonocore MG.
Journal of Dental Research, 34(6), 849-853 (1955)
FTIR and 31 P-NMR spectroscopic analyses of surface species in phosphate-catalyzed lactic acid conversion.
Gunter GC, et al.
J. Catal., 164(1), 207-219 (1996)
Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)
D S Marinier et al.
Journal of lipid research, 29(9), 1237-1243 (1988-09-01)
In order to study the lipid composition of human white matter, we have developed a 31P NMR spectroscopy method, which allows the determination and quantitation of the main phospholipids found in biological membranes. The technique is based upon the use
J M Fujitaki et al.
Biochemistry, 20(12), 3658-3664 (1981-06-09)
Phosphorus-31 nuclear magnetic resonance (31P NMR) is used to investigate acid-labile phosphorylation of histone H4. 31P NMR detects phosphorylated histidine residues in in vitro enzymatically phosphorylated H4. The source of kinase is nuclei from either regenerating rat liver or Walker-256
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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