230731
Nitromethane
ReagentPlus®, ≥99.0%
Sinónimos:
Nitrocarbol
Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
About This Item
Fórmula empírica (notación de Hill):
CH3NO2
Número de CAS:
Peso molecular:
61.04
Beilstein:
1698205
Número CE:
Número MDL:
Código UNSPSC:
12352102
ID de la sustancia en PubChem:
NACRES:
NA.21
Ensayo:
≥99.0%
bp:
101.2 °C (lit.)
presión de vapor:
2.7 mmHg
Productos recomendados
densidad de vapor
2.1 (vs air)
Nivel de calidad
presión de vapor
2.7 mmHg
Línea del producto
ReagentPlus®
Ensayo
≥99.0%
Formulario
liquid
temp. de autoignición
784 °F
lim. expl.
7.3 %, 33 °F
índice de refracción
n20/D 1.382 (lit.)
pH
6.4 (20 °C, 0.01 g/L)
bp
101.2 °C (lit.)
mp
−29 °C (lit.)
densidad
1.127 g/mL at 25 °C (lit.)
cadena SMILES
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
Clave InChI
LYGJENNIWJXYER-UHFFFAOYSA-N
¿Está buscando productos similares? Visita Guía de comparación de productos
Descripción general
Nitromethane (CH3NO2) is the simplest nitro organic compound used for a wide range of applications, including as polar solvents to racing fuel. It serves as a solvent for organic chemistry and as a valuable building block for various useful compounds like nitroalkanes, β-nitroalcohols, nitroalkenes, carbonyl compounds, amines, and heterocycles. In industry, nitromethane can be used to stabilize halogenated hydrocarbons.
Aplicación
Nitromethane can be used:
- As a reagent in the synthesis of 3-nitroindoles by arylation with N-(2-bromoaryl) imidates using palladium catalyst.
- As a cyanating reagent for the synthesis of thiocyanates in presence of base (KOAc) and iodine.
- In the preparation of cobalt cage complexes from polyamines and formaldehyde.
- As a solvent in the preparation of β-substituted γ-nitroaldehydes by enantioselective cross-coupling of β-arylated or γ,δ-unsaturated aldehydes using oxidizing agent DDQ (2,3-dichloro-5,6-dicyanoquinone) and catalyst diphenylprolinol silyl ether.
Características y beneficios
Nitromethane as high energy monopropellant exhibits
- Low toxicity.
- High specific impulse.
Información legal
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
Código de clase de almacenamiento
4.1A - Other explosive hazardous materials
Clase de riesgo para el agua (WGK)
WGK 2
Punto de inflamabilidad (°F)
95.0 °F - closed cup
Punto de inflamabilidad (°C)
35 °C - closed cup
Elija entre una de las versiones más recientes:
¿Ya tiene este producto?
Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Los clientes también vieron
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Atanu Bhattacharya et al.
The Journal of chemical physics, 136(2), 024321-024321 (2012-01-21)
Decomposition of electronically excited nitro-containing molecules with different X-NO(2) (X = C, N, O) moieties has been intensively investigated over the past decades; however, their decomposition behavior has not previously been compared and contrasted. Comparison of their unimolecular decomposition behavior
Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.
Póngase en contacto con el Servicio técnico