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Merck

270970

Sigma-Aldrich

Pyridine

anhydrous, 99.8%

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About This Item

Fórmula empírica (notación de Hill):
C5H5N
Número de CAS:
Peso molecular:
79.10
Beilstein/REAXYS Number:
103233
EC Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.21
grade:
anhydrous
assay:
99.8%
bp:
115 °C (lit.)
vapor pressure:
10 mmHg ( 13.2 °C)
20 mmHg ( 25 °C)
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grade

anhydrous

Quality Level

vapor density

2.72 (vs air)

vapor pressure

10 mmHg ( 13.2 °C)
20 mmHg ( 25 °C)

assay

99.8%

form

liquid

autoignition temp.

899 °F

expl. lim.

12.4 %

impurities

<0.003% water
<0.005% water (100 mL pkg)

evapn. residue

<0.0005%

color

colorless

refractive index

n20/D 1.509 (lit.)

pH

~8.81 (20 °C)

bp

115 °C (lit.)

mp

−42 °C (lit.)

density

0.978 g/mL at 25 °C (lit.)

SMILES string

C1=CN=CC=C1

InChI

1S/C5H5N/c1-2-4-6-5-3-1/h1-5H

Inchi Key

JUJWROOIHBZHMG-UHFFFAOYSA-N

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General description

Pyridine is a basic N-heterocyclic compound. It acts as nitrogen donor ligand and forms many metal-pyridine complexes. Its complexes having tetrahedral and octahedral geometries can be differentiated by infra-red spectral investigations.[1]

Application

Pyridine (py) may be used in the preparation of vanadium oxide nanoparticles[2] and iron benzenedicarboxylates, Fe(OH)(BDC)(py)0.85 (BDC = 1,4-benzenedicarboxylate, py = pyridine).[3] It may be employed as catalyst in Knoevenagel condensation reaction.[4]
Pyridine may be used as a base for the conversion of:
  • Alkyltrichlorosilanes to trimethoxyalkylsilanes, which are used as precursors for preparing alkylsilicates.[5]
  • 1-Indanone to 1-indanone oxime, which can undergo reductive ring-expansion to form tetrahydroquinoline.[6]

It may also be used to catalyze the borylation reaction of haloarenes to form arylboronates without using transition metal catalysts.[7]

also commonly purchased with this product

Referencia del producto
Descripción
Precios

suggested gloves for splash protection

Referencia del producto
Descripción
Precios

Pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

68.0 °F - closed cup

flash_point_c

20 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Pyridine-catalyzed radical borylation of aryl halides
Zhang L & Jiao L
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Questions

1–3 of 3 Questions  
  1. Is this compound derived from plants?

    1 answer
    1. This product is typically synthetically manufactured and not plant-derived. However, the origin may vary on a lot-to-lot basis. More information may be found in the lot-specific Certificate of Origin. Please navigate to the ‘DOCUMENTATION’ section of the Product Detail Page to access a Certificate under the ‘Certificate of Origin’ tab:
      https://www.sigmaaldrich.com/product/sial/270970#product-documentation

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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