900402

SLAP HydroQuinoxaline

95%

• Sinónimos: trans-N¹-Benzyl-N¹-((trimethylsilyl)methyl)cyclohexane-1,2-diamine
• Fórmula empírica (notación de Hill): C₁₇H₃₀N₂Si
• Peso molecular: 290.52
• Código UNSPSC: 12352103
• NACRES: NA.22

Propiedades

• Ensayo: 95%
• Formulario: liquid
• índice de refracción: n/D 1.5222
• densidad: 0.961 g/mL
• grupo funcional: amine; phenyl
• temp. de almacenamiento: −20°C

Descripción

Aplicación

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

Otras notas

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

Información de seguridad

• Código de clase de almacenamiento: 10 - Combustible liquids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): >230.0 °F
• Punto de inflamabilidad (°C): > 110 °C