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Sigma-Aldrich

Zirconium(IV) acetylacetonate

97%

Sinónimos:

2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate

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About This Item

Fórmula lineal:
Zr(C5H7O2)4
Número de CAS:
17501-44-9
Peso molecular:
487.66
Beilstein/REAXYS Number:
4160373
EC Number:
241-510-5
MDL number:
MFCD00000036
UNSPSC Code:
12352103
PubChem Substance ID:
24860510
NACRES:
NA.23

Quality Level

200

assay

97%

form

powder

reaction suitability

core: zirconium
reagent type: catalyst

SMILES string

CC(=O)\C=C(\C)O[Zr](O\C(C)=C/C(C)=O)(O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/4C5H8O2.Zr/c4*1-4(6)3-5(2)7;/h4*3,6H,1-2H3;/q;;;;+4/p-4/b4*4-3-;

Inchi Key

FPFOSIXCIBGKOH-MTOQALJVSA-J

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General description

Zirconium(IV) acetylacetonate is a white crystalline organometallic solid widely used as a sol-gel precursor to synthesize Zirconium-based nanomaterials and thin films. It also finds application in the field of catalysis and polymer synthesis.

Application

Zirconium(IV) acetylacetonate can be used:
  • As a sol-gel precursor to synthesize zirconia nanoparticles with photocatalytic activity.
  • As an additive to improve the performance of the electron transport layer in perovskite solar cells.
  • To synthesize as-prepared zirconium acetylacetonate (a-ZrAcac) film as a cathode buffer layer in polymer solar cells. It exhibited an average power conversion efficiency (PCE) of 8.75% which is significantly improved than that of the devices with traditional Ca/Al cathode.
  • To synthesize high-κ zirconium oxide gate dielectric for Organic Field-Effect Transistors at low voltage operation.
  • To fabricate the conductive interlayers for quantum dot light-emitting devices(QLEDs), which enhances quantum efficiency, power efficiency, and longer operational lifetimes.
  • As a ring-opening initiator to synthesize biodegradable polyacids.
  • As a catalyst to synthesize polylactide terpolymers.

Pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

hcodes

H228,H302

Hazard Classifications

Acute Tox. 4 Oral - Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

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Visite la Librería de documentos

Trzaska, S.T. et al.
Chemistry of Materials, 11, 130-130 (1999)
Room-temperature fabrication of ultrathin oxide gate dielectrics for low-voltage operation of organic field-effect transistors
Young Min Park, et al.
Advanced Materials, 23, 971-974 (2011)
High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer
Zhan'ao Tan, et al.
Scientific Reports, 4, 4691-4691 (2014)
Zirconium (IV) acetylacetonate: Ring-opening initiator mediating one-step synthesis of biodegradable polyacids
Piotr Dobrzy'nski, et al.
Advances in Polymer Technology, 2019-2019 (2019)
Synthesis and properties of polylactide terpolymers P(LLA-TMC-GA) catalyzed by zirconium(IV)acetylacetonate
Shaohua Wen, et al
Applied Organometallic Chemistry, 32, e4177-e4177 (2018)
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