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Sigma-Aldrich

Ammonium perrhenate

≥99%

Sinónimos:

Metaperrhenic acid ammonium salt, Rhenium standard solution

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About This Item

Fórmula lineal:
NH4ReO4
Número de CAS:
13598-65-7
Peso molecular:
268.24
EC Number:
237-075-6
MDL number:
MFCD00012377
UNSPSC Code:
12352302
PubChem Substance ID:
24859053
NACRES:
NA.23

Quality Level

100

assay

≥99%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: rhenium

density

3.97 g/mL at 25 °C (lit.)

SMILES string

N.O[Re](=O)(=O)=O

InChI

1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1

Inchi Key

XPSXHXWHJAIQJR-UHFFFAOYSA-M

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General description

Ammonium perrhenate is a white crystalline solid soluble in ethanol and water. It is a weak oxidizer and widely used as a Re precursor in nanomaterial synthesis and Re-based catalyst preparation.

Application

Ammonium perrhenate used:
  • As a rhenium source to prepare Re nanoparticles for catalytic decomposition of ammonium perchlorate.
  • To synthesize ReS2 through a direct sulfidation reaction, for the fabrication of field effect transistors (FETs), digital logic devices, humidity sensors, and rechargeable supercapacitors.
  • As a precursor to prepare the heterogeneous catalysts for organic transformations.
  • An excellent precursor for the fabrication of ReOx/TiO2 recyclable solidcatalyst for deoxydehydration. For at least six runs in a row, the catalyst demonstrated catalyticactivity, selectivity, and stability without deactivation.

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Proceedings of the National Academy of Sciences of the United States of America, 111(33), 12013-12018 (2014-08-06)
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