If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
205699
Paladio sobre carbono
extent of labeling: 10 wt. % loading, matrix activated carbon support
Sinónimos:
Pd/C
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About This Item
Productos recomendados
Formulario
powder
Nivel de calidad
idoneidad de la reacción
core: palladium
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
características de los productos alternativos más sostenibles
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
Extensión del etiquetado
10 wt. % loading
Matriz
activated carbon support
categoría alternativa más sostenible
cadena SMILES
[Pd]
InChI
1S/Pd
Clave InChI
KDLHZDBZIXYQEI-UHFFFAOYSA-N
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Descripción general
Aplicación
- Reacción de Stille
- Reacciones de hidrogenación
- Reacción de acoplamiento cruzado de Suzuki-Miyaura y reacciones de Heck-Mizoroki
- Desoxigenación
- Reacciones de oxidación
- Reacciones de acoplamiento
También puede utilizarse como
- catalizador para la hidrodecloración del diclorodifluorometano (CCL2F2), que es un gas de efecto invernadero conocido[1],
- catalizador de las reacciones de Heck de haluros de arilo en líquidos iónicos[2]
- catalizador anódico para la fabricación de pilas de combustible de ácido fórmico directo (DFAFC)[3]
- electrocatalizador rentable para la oxidación del metanol[4]
- en la hidrogenación catalítica de hidruros químicos para la producción de hidrógeno[5]
- catalizador en la reacción de Suzuki-Mayaura[6]
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Elija entre una de las versiones más recientes:
Certificados de análisis (COA)
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Los clientes también vieron
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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How much is the palladium on carbon
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This product is 10 wt.% Palladium on activated carbon support.
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We are using this catalyst in our work. Do you have a particle distribution range for the activated carbon used?
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Unfortunately, based on the specification sheet for Product 205699, a specification for the particle distribution range is not tested. This information is unavailable.
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I wanted to ask how activated carbon was loaded with Pd. I appreciate if you could provide the preparation method.
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This product is an M-Clarity level 200 item. The method of preparation is considered proprietary for Products of this level.
However, you may find it helpful to read this article:
https://www.masterorganicchemistry.com/2011/11/25/palladium-on-carbon-pdc/Helpful?
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What is the particle size of Product 205699, Palladium on carbon?
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We expect the product to conform to the following: approximately 90% <60 μm and 10% <5 μm with an average particle size of 15 μm.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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Is Product 205699, Palladium on carbon, reduced or unreduced?
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It is reduced, but it can oxidize pretty readily.
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What is the surface area of Product 205699, Palladium on carbon?
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The surface area of the carbon used as the support is 750-1000 m2 /g. They do not test the surface area of the finished catalyst.
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What is the activity of Product 205699, Palladium on carbon? How is the activity tested? Is it a guaranteed value?
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There is a fairly large variance in activity reported by the manufacturer on this material (from less than 50 ml/min to more than 100 ml/min). Activity is not a specification but reported on the Certification of Analysis for further information. Activity is measured by the hydrogen reduction of nitrobenzene.
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