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383074

Sigma-Aldrich

Bismuth(III) nitrate pentahydrate

ACS reagent, ≥98.0%

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About This Item

Formula condensata:
Bi(NO3)3 · 5H2O
Numero CAS:
10035-06-0
Peso molecolare:
485.07
Numero CE:
233-791-8
Codice UNSPSC:
12352302
ID PubChem:
24863932
NACRES:
NB.24

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Grado

ACS reagent

Livello qualitativo

200

Saggio

≥98.0%

Stato

(Powder or Crystals or Solid or Chunks)

Impiego in reazioni chimiche

reagent type: catalyst
core: bismuth

Impurezze

≤0.005% insolubles

P. ebollizione

75-80 °C (lit.)

Punto di fusione

30 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

Cationi in tracce

Ag: ≤0.001%
As: ≤0.001%
Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.002%

Stringa SMILE

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
DPLOIMSBRDLLRI-UHFFFAOYSA-N

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Descrizione generale

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.[1]

Applicazioni

Bismuth(III) nitrate pentahydrate may be used in the following processes:
  • Conversion of thioamides and thioureas to their oxo derivatives.[2]
  • Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.[3]
  • Synthesize coumarins by Pechmann condensation under solvent free conditions.[1]
  • As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.[4]
  • As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.[5]
  • As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.[6]
  • Synthesis of glycosides by Fischer glycosylation of unprotected sugars.[7]
  • Synthesis of bismuth oxide (Bi2O3) nanoparticles.[8]
  • Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.[9]
  • Selective oxidation of sufides to sulfoxides.[10]

Pittogrammi

Flame over circleCorrosion
GHS03,GHS05

Avvertenze

Danger

Indicazioni di pericolo

H272,H318

Classi di pericolo

Eye Dam. 1 - Ox. Sol. 2

Codice della classe di stoccaggio

5.1B - Oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

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Certificati d'analisi (COA)

Lot/Batch Number
MKCV9315
MKCW5564
MKCV1159
MKCT5456
MKCV4369

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Bismuth (III) nitrate pentahydrate: a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Mohammadpoor-Baltork I, et al.
Tetrahedron Letters, 44(3), 591-594 (2003)
Rapid three-component synthesis of pyrimidine and pyrimidinone derivatives in the presence of Bi(NO3)3?5H2O as a mild and highly efficient catalyst.
Zahedifar M and Sheibani H.
Research on Chemical Intermediates, 41(1), 105-111 (2015)
Investigations on the properties of pure and rare earth modified bismuth ferrite ceramics.
Kazhugasalamoorthy S, et al.
J. Alloy Compounds, 493(1), 569-572 (2010)
Bismuth (III) nitrate pentahydrate-a mild and inexpensive reagent for synthesis of coumarins under mild conditions.
Alexander VM, et al.
Tetrahedron Letters, 46(40), 6957-6959 (2005)
Bismuth Nitrate Pentahydrate: A Convenient Reagent for the Oxidation of Hantzsch 1,4-Dihydropyridines.
Mashraqui SH and Karnik MA.
Synthesis, 1998(5), 713-714 (1998)
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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