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Sigma-Aldrich

Bismuth(III) chloride

reagent grade, ≥98%

Sinonimo/i:

Bismuth trichloride, Trichlorobismuth

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About This Item

Formula empirica (notazione di Hill):
BiCl3
Numero CAS:
Peso molecolare:
315.34
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.21
Prezzi e disponibilità al momento non sono disponibili

Grado

reagent grade

Saggio

≥98%

Stato

powder, chunks or granules

Impiego in reazioni chimiche

reagent type: catalyst
core: bismuth

P. ebollizione

447 °C (lit.)

Punto di fusione

230-232 °C (lit.)

Stringa SMILE

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
JHXKRIRFYBPWGE-UHFFFAOYSA-K

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Descrizione generale

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine. [1]

Applicazioni

Bismuth(III) chloride may be used as a catalyst in the following processes:
  • Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.[2]
  • Preparation of thiiranes from oxiranes using ammonium thiocyanate.[3]
  • Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.[4]
  • Allylation of secondary benzyl alcohols with allyltrimethylsilane.[5]
  • [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.[6]

Pittogrammi

Exclamation mark

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Certificati d'analisi (COA)

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I clienti hanno visto anche

Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
Bismuth (III) Chloride-Catalyzed Three-Component Coupling: Synthesis of a-Amino Phosphonates.
Zhan ZP and Li JP.
Synthetic Communications, 35(19), 2501-2508 (2005)
Bismuth (iii) Chloride Mediated Michaelis-Arbuzov Reaction: A Facile Synthesis of Substituted Arylphosphonates/Phosphinates and Bioactivity Evaluation.
Subramanyam C, et al.
Phosph. Sulfur Relat. Elem. (2015)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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