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78780

Sigma-Aldrich

Phenyl isothiocyanate

for HPLC derivatization, the detection of alcohols and amines, ≥99.0%

Sinonimo/i:

PITC

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About This Item

Formula condensata:
C6H5NCS
Numero CAS:
103-72-0
Peso molecolare:
135.19
Beilstein:
471392
Numero CE:
203-138-1
Numero MDL:
MFCD00004798
Codice UNSPSC:
12352100
ID PubChem:
57652756
NACRES:
NA.21

Livello qualitativo

200

Saggio

≥99.0%

Stato

liquid

Qualità

for HPLC derivatization, the detection of alcohols and amines

Indice di rifrazione

n20/D 1.649
n20/D 1.6515 (lit.)

P. ebollizione

218 °C (lit.)

Punto di fusione

−21 °C (lit.)

Solubilità

water: insoluble

Densità

1.13 g/mL at 20 °C
1.132 g/mL at 20 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

S=C=Nc1ccccc1

InChI

1S/C7H5NS/c9-6-8-7-4-2-1-3-5-7/h1-5H
QKFJKGMPGYROCL-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Phenyl isothiocyanate is an aromatic isothiocyanate. It participates in dehydration reactions of alcohols. It is widely used for synthesis of various biologically important heterocyclic compounds.

Applicazioni

Derivatizing reagent for primary and secondary amines. Used in sequencing peptides by Edman degradation and in amino acid analyses by HPLC.
Phenyl isothiocyanate may be employed as a derivatization reagent for high-performance liquid chromatographic (HPLC) analysis of various amphetamine derivatives in body fluids.

Avvertenza

Store under Argon

Prodotti consigliati

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Avvertenze

Danger

Indicazioni di pericolo

H301,H314,H317,H334

Classi di pericolo

Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

190.4 °F - closed cup

Punto d’infiammabilità (°C)

88 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCM8732
BCCM7882
BCCK3507
BCCG8125
BCCD5138

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Sigma-Aldrich

C105406

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Supelco

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Supelco

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D-(+)-Neopterin ≥97.5% (sum of enantiomers, HPLC)

Sigma-Aldrich

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Benzyl isothiocyanate 98%

Sigma-Aldrich

252492

Benzyl isothiocyanate

Amino Acid Standard analytical standard

Supelco

AAS18

Amino Acid Standard

Dopamine-1,1,2,2-d4 hydrochloride analytical standard

Supelco

73483

Dopamine-1,1,2,2-d4 hydrochloride

One-pot dehydrations using phenyl isothiocyanate.
Majetich G, et al.
Tetrahedron Letters, 56(23), 3326-3329 (2015)
Amin Zolali et al.
Combinatorial chemistry & high throughput screening, 17(7), 610-613 (2014-03-19)
An efficient, one-pot and three-component synthesis of biologically important heterocyclic compounds is described from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride at room temperature without the need to use any catalyst.
Determination of phenylisothiocyanate derivatives of amphetamine and its analogues in biological fluids by HPLC-APCI-MS or DAD.
Bogusz MJ, et al.
Journal of Analytical Toxicology, 21(1), 59-69 (1997)
Tomoyuki Oe et al.
Rapid communications in mass spectrometry : RCM, 24(2), 173-179 (2009-12-17)
This manuscript describes the results of a preliminary experiment performed as 'proof of concept' of a novel approach to absolute quantitation of proteins without the use of standard proteins. Absolute quantitation remains a challenging issue in the proteomics field. Therefore
Akira Murakami et al.
BioFactors (Oxford, England), 30(1), 1-11 (2008-01-17)
Osteoclastogenesis is induced by differentiation of hemopoietic cells of monocyte-macrophage lineage into bone-resorbing osteoclasts. The process is initiated by receptor activator of NF-kappaB ligand (RANKL) and resultant activation of mitogen-activated protein kinases (MAPK), including extracellular signal-regulated kinase (ERK)1/2, as well
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