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Sigma-Aldrich

Bis(cyclopentadienyl)cobalt(II)

Sinonimo/i:

Cobaltocene

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About This Item

Formula condensata:
Co(C5H5)2
Numero CAS:
1277-43-6
Peso molecolare:
189.12
Numero CE:
215-061-0
Numero MDL:
MFCD00013749
Codice UNSPSC:
12352103
ID PubChem:
24860617
NACRES:
NA.23

Forma fisica

powder or crystals
solid

Impiego in reazioni chimiche

core: cobalt

Punto di fusione

176-180 °C (dec.) (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

[Co].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Co/c2*1-2-4-5-3-1;/h2*1-5H;
PXFGMRZPRDJDEK-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Bis(cyclopentadienyl)cobalt(II) also known as cobaltocene, is an organometalliccompound that is widely used in the field of polymer synthesis, cobaltnanomaterials, and redox flow batteries.

Applicazioni

Bis(cyclopentadienyl)cobalt(II) can be used:
  • As a dopant to prepare encapsulated carbon nanotubes with high thermoelectric conversion efficiency.
  • As a CVD precursor to fabricate cobalt oxide thin films for various applications.
  • As a redox-active anode species in Li-based redox flow batteries to achieve higher energy densities and energy efficiencies.
  • As a catalyst for controlled/“living” radical polymerization of methylmethacrylate.

Pittogrammi

FlameHealth hazard
GHS02,GHS08

Avvertenze

Danger

Indicazioni di pericolo

H228,H317,H334,H341,H351

Classi di pericolo

Carc. 2 - Flam. Sol. 2 - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

Codice della classe di stoccaggio

4.1B - Flammable solid hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificati d'analisi (COA)

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A high-performance all-metallocene-based, non-aqueous redox flow battery
Yu Ding, et al.
Energy & Environmental Science, 10, 491-497 (2017)
F Li et al.
Chemical science, 9(30), 6379-6389 (2018-10-13)
A series of NO-bound, iron-functionalized polyoxovanadate-alkoxide (FePOV-alkoxide) clusters have been synthesized, providing insight into the role of multimetallic constructs in the coordination and activation of a substrate. Upon exposure of the heterometallic cluster to NO, the vanadium-oxide metalloligand is oxidized
Development of n-type cobaltocene-encapsulated carbon nanotubes with remarkable thermoelectric property
Takahiro Fukumaru, et al.
Scientific Reports, 5, 7951-7951 (2015)
Jacob M Clary et al.
Nanotechnology, 31(17), 175703-175703 (2020-01-09)
Highly dispersed cobalt atoms were deposited on porous alumina particles using atomic layer deposition (ALD) with a CoCp2/H2 chemistry at approximately 7 wt%. H2 did not completely reduce the cyclopentadienyl organic ligands bound to deposited Co atoms at ALD reaction
Thin films of cobalt oxide deposited on high aspect ratio supports by atomic layer deposition
Madeleine Diskus, et al
Chem. Vap. Deposition, 17, 135-140 (2011)
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