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Merck

648531

Sigma-Aldrich

N,N-Dimethylformamid

suitable for HPLC, ≥99.9%

Synonym(e):

DMF, NSC 5356

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About This Item

Lineare Formel:
HCON(CH3)2
CAS-Nummer:
Molekulargewicht:
73.09
Beilstein:
605365
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12190000
PubChem Substanz-ID:

Dampfdichte

2.5 (vs air)

Qualitätsniveau

Dampfdruck

2.7 mmHg ( 20 °C)

Assay

≥99.9%

Form

liquid

Selbstzündungstemp.

833 °F

Expl.-Gr.

15.2 %

Methode(n)

HPLC: suitable

Verunreinigungen

≤0.030% water

Abdampfrückstand

≤0.0005%

Brechungsindex

n20/D 1.430 (lit.)

bp

153 °C (lit.)

mp (Schmelzpunkt)

−61 °C (lit.)

Dichte

0.944 g/mL (lit.)

Absorption

0.010 at 340 nm
0.010 at 400 nm
0.05 at 310 nm
0.10 at 295 nm
0.30 at 275 nm
1.00 at 270 nm

Anwendung(en)

food and beverages

SMILES String

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

InChIKey

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

N,N-Dimethylformamide (DMF) is the commonly employed solvent for chemical reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.

Anwendung

Lösungsmittel für viele hydrophobe, organische Verbindungen.

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Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

135.5 °F - closed cup

Flammpunkt (°C)

57.5 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis and electrochemical characterization of aPEO-based polymer electrolytes.
Rodrigues LC, et al.
Journal of Solid State Electrochemistry, 16(4), 1623-1629 (2012)
Measurements and molecular interactions for N,N-dimethylformamide with ionic liquid mixed solvents.
Attri P, et al.
The Journal of Physical Chemistry B, 114(18), 6126-6133 (2010)
The dynamics of liquid formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide. A dielectric relaxation study.
Barthel J, et al.
Journal of Molecular Liquids, 98, 51-69 (2002)
Volumetric properties of ammonium nitrate in N,N-dimethylformamide.
Vranes M, et al.
The Journal of Chemical Thermodynamics, 54, 245-249 (2012)
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined

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