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V1902

Sigma-Aldrich

Vinylbromid

98%

Synonym(e):

Bromethylen

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About This Item

Lineare Formel:
CH2=CHBr
CAS-Nummer:
593-60-2
Molekulargewicht:
106.95
Beilstein:
1361370
EG-Nummer:
209-800-6
MDL-Nummer:
MFCD00000183
UNSPSC-Code:
12162002
PubChem Substanz-ID:
24900722
NACRES:
NA.23

Dampfdichte

3.8 (15 °C, vs air)

Qualitätsniveau

200

Dampfdruck

1551 mmHg ( 37.8 °C)

Assay

98%

Selbstzündungstemp.

986 °F

Enthält

200 ppm monomethyl ether hydroquinone as inhibitor

Expl.-Gr.

15 %

bp

16 °C/750 mmHg (lit.)

mp (Schmelzpunkt)

−139 °C (lit.)

Dichte

1.517 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

BrC=C

InChI

1S/C2H3Br/c1-2-3/h2H,1H2

InChIKey

INLLPKCGLOXCIV-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

  • FTIR and Raman Spectroscopy Study of Soot Deposits: Investigates soot formation during the infrared multiphoton dissociation of vinyl bromide, suggesting potential applications in materials science regarding soot characteristics (Samoudi et al., 2022).
  • Nickel-Catalyzed Reductive Cross-Coupling: Describes a method for coupling vinyl bromides with unactivated alkyl halides, highlighting its utility in synthetic organic chemistry for creating complex molecules (Gong et al., 2017).
  • Silver-Promoted Synthesis of Vinyl Sulfones: This study explores the reactivity of vinyl bromides with sulfonyl hydrazides under aqueous conditions, applicable to pharmaceutical synthesis due to the biorelevance of sulfones (Zhang et al., 2020).
  • Visible Light on Vinyl Halides: Examines the photocatalytic properties of vinyl bromides, which could influence the development of green chemistry applications (Pagire et al., 2020).
  • Palladium Catalyzed Cross-Coupling of Diboronates: Focuses on the reactions of vinyl bromides with diboronates, offering insights into new methodologies for constructing biologically active compounds (Li et al., 2014).

Sonstige Hinweise

V1902-100 g, V1902-900 g, and 1902-2.2 kg includes installed 316SS needle valve.

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Stainless steel hose adapter Z146838 or stainless steel body mini gas regulator Z513547 is recommended.

Regulierungsbehörde

Produkt-Nr.
Beschreibung
Preisangaben

Z513547

Aldrich® Mini-Gasregler, stainless steel body

Schlaucholive

Produkt-Nr.
Beschreibung
Preisangaben

Z146838

Schlauchadapter, stainless steel

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Carc. 1B - Flam. Gas 1A - Press. Gas Liquefied gas

Lagerklassenschlüssel

2A - Gases

WGK

WGK 3

Flammpunkt (°F)

55.4 °F

Flammpunkt (°C)

13 °C

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Xiaodan Zhao et al.
The Journal of organic chemistry, 71(10), 3988-3990 (2006-05-06)
(E/Z)-isomers containing vinyl bromides were stereoselectively carbonylated to the corresponding (E)-alpha,beta-ethylenic carboxylic acids in the ionic liquid [BMIM]PF6. Vinyl dibromides also underwent hydroxycarbonylation to give monoacids. The products are pure by proton NMR spectroscopic determination without purification by silica gel
Piotr Pawluć et al.
Organic letters, 11(15), 3390-3393 (2009-07-04)
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-beta-aryl vinyl iodides and (E)-beta-aryl vinyl bromides from styrenes based on sequential ruthenium-catalyzed silylative coupling-N-halosuccinimide-mediated halodesilylation reactions is reported.
Carcinogenicity of 1,3-butadiene, ethylene oxide, vinyl chloride, vinyl fluoride, and vinyl bromide.
Yann Grosse et al.
The Lancet. Oncology, 8(8), 679-680 (2007-08-30)
Cheon-Gyu Cho et al.
Organic letters, 7(16), 3569-3572 (2005-07-29)
An effective, readily scalable two-step synthesis of trisubstituted (E)-vinyl bromides involving bromination of alpha,beta-unsaturated lactones followed by hydrolytic fragmentation has been developed. Several trisubstituted (E)-vinyl bromides, including multigram quantities of (+)-(E)-4-bromo-2-methyl-3-pentenol, a synthetic intermediate required for the C(8)-C(11) moieties of
Hsin-Lun Kao et al.
Organic letters, 13(19), 5204-5207 (2011-09-02)
The synthesis of vinyl sulfides through the coupling reaction of thiols with vinyl iodides, bromides, and chlorides is described. The thiols can couple with aryl iodides in the presence of only 0.5 mol % Cu(2)O without the need for an
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