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86578

Sigma-Aldrich

Tetraethylorthosilikat

≥99.0% (GC)

Synonym(e):

Orthokieselsäure-Tetraethylester, Silizium-Tetraethoxid, TEOS, Tetraethoxysilan, Tetraethoxysilizium(IV), Tetraethylsilikat

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250 ML
CHF 44.10
1 L
CHF 133.00

CHF 44.10


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250 ML
CHF 44.10
1 L
CHF 133.00

About This Item

Lineare Formel:
Si(OC2H5)4
CAS-Nummer:
Molekulargewicht:
208.33
Beilstein:
1422225
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22
bp:
168 °C (lit.)

CHF 44.10


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Dampfdichte

7.2 (vs air)

Qualitätsniveau

Dampfdruck

<1 mmHg ( 20 °C)

Assay

≥99.0% (GC)

Form

liquid

Methode(n)

GC/GC: suitable

Brechungsindex

n20/D 1.382 (lit.)
n20/D 1.383

bp

168 °C (lit.)

Dichte

0.933 g/mL at 20 °C (lit.)

SMILES String

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

InChIKey

BOTDANWDWHJENH-UHFFFAOYSA-N

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Allgemeine Beschreibung

Tetraethylorthosilikat (TEOS) ist ein anorganisches Material, das als Siliziumquelle für die Synthese von Materialien auf Siliziumbasis wie Siliziumdioxid,[1] Siliziumoxycarbid,[2] Silanol,[3] Siloxanpolymere[4] und Organosilizium-Dünnschichten[5] für eine Vielzahl von Anwendungen eingesetzt werden kann. Es kann außerdem bei der Synthese von Mischmembranen und der Herstellung von Aerogel verwendet werden.[6] Andere Anwendungen sind zum Beispiel Beschichtungen für Teppiche und andere Gegenstände.[7]

Anwendung

Häufig als Vorstufe zur Herstellung von Xerogel verwendet
Tetraethylorthosilikat (TEOS) kann verwendet werden:
  • Als Reagenz zusammen mit Eisenchlorid bei der Synthese von Dihydropyrimidinonen.[8]
  • Als Modifikator bei der Herstellung des für Feuchtesensoren genutzten Poly(2-acrylamido-2-methylpropansulfonat) (Poly-AMPS).[9]
  • Als Medium zur Synthese von Triarylaminen und Diarylethern mittels kupferkatalysierter, ligandenfreier Ullmann-Reaktion. [10]
  • Als Vorstufe für die Herstellung von Kieselsäure-Xerogel, das in pharmazeutischen Wirkstoffträgern Anwendung findet.[11]
  • Als Vorstufe für die Synthese von kugelförmigen Kieselsäurepartikeln nach dem Stöber-Verfahren.[12]

Wechselwirkung mit Dodecylamin bei der Bildung von Interkalationsverbindungen von H+-Magadiit und Verwendung in einer Studie über bioaktive Gläser aus Mischmetall.

Piktogramme

FlameExclamation mark

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

113.0 °F - closed cup

Flammpunkt (°C)

45 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

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Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Ullmann reaction in tetraethyl orthosilicate: a novel synthesis of triarylamines and diaryl ethers
Zhao Y, et al.
Chemical Communications (Cambridge, England), 30(449), 3186-3188 (2007)
Silica xerogels as pharmaceutical drug carriers
Quintanar-Guerrero D, et al.
Expert Opinion on Drug Delivery, 5(6), 485-498 (2009)
The Organosilicon thin Film Deposited Using an Atmospheric Pressure Dual-Frequency 50 kHz/33 MHz Frequency MicroPlasma Jet
Yuan QH, et al.
Contributions to Plasma Physics, 56(9), 870-877 (2016)
Use of poly (2-acrylamido-2-methylpropane sulfonate) modified with tetraethyl orthosilicate as sensing material for measurement of humidity
Su PG, et al.
Analytica Chimica Acta, 1-2(449), 103-109 (2001)
Ferric chloride/tetraethyl orthosilicate as an efficient system for synthesis of dihydropyrimidinones by Biginelli reaction
Cepanec I, et al.
Tetrahedron, 17(61), 4275-4280 (2005)

Questions

1–10 of 12 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the thermal conductivity of TEOS?

    1 answer
    1. Unfortunately, the thermal conductivity of this product is not determined.

      Helpful?

  4. What is the electrical conductivity or resistivity of TEOS

    1 answer
    1. This product is not tested for electrical conductivity. The compound is not expected to be a conductive material. The presence of TEOS in various coatings may impact the conductivity or resistivity of a given target compound, such as a metallic nanoparticle. See the links below to review articles that may be of interest:
      https://www.researchgate.net/figure/Effect-of-the-addition-of-TEOS-on-a-density-b-resistivity-c-residual-magnetic_fig5_371096514
      https://link.springer.com/article/10.1007/s12633-019-00180-y

      Helpful?

  5. According to the theise, TEOS was used in units of g. Do you sell powder or solid TEOS?

    1 answer
    1. Tetraethyl orthosilicate is only available in the liquid state. The melting point of the pure compound is -82.5 °C. The density of this material is 0.933 g/mL.
      See the link below to review the PubChem profile.
      https://pubchem.ncbi.nlm.nih.gov/compound/Tetraethyl-orthosilicate#section=Melting-Point

      Helpful?

  6. What type of applications can Product No. 86578, Tetraethyl orthosilicate (TEOS), be used in?

    1 answer
    1. TEOS can be used to synthesize sol-gels or aerogels.

      Helpful?

  7. How do you create a sol-gel with Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. TEOS can be polymerized with water; the polymerization is based on the hydrolysis or the Si-O-Et groups through forming networks linked by Si-O-Si groups.

      Helpful?

  8. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

      Helpful?

  9. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  10. What are the applications of sol-gels formed from Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. One of the most improtant application of the sol-gel process is the snythesis of zeolites. Other applications are optical ceramic materials or functionalized biosensors.

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1–10 of 12 Questions  

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