749125

Cobalt(II) oxo pivalate

• Synonym(e): Basic cobalt(II) pivalate, Cobalt, hexakis[μ-(2,2-dimethylpropanoato-κO:κO′)]hexakis[μ₃-(2,2-dimethylpropanoato-κO:κO:κO′)]di-μ₄-oxoocta-, Tetrameric Co cluster
• Empirische Formel (Hill-System): C₆₀H₁₀₈Co₈O₂₆
• CAS-Nummer: 301663-94-5
• Molekulargewicht: 1716.95
• MDL-Nummer: MFCD22200509
• UNSPSC-Code: 26111700
• PubChem Substanz-ID: 329765968
• NACRES: NA.23

Eigenschaften

• Form: powder
• Grünere Alternativprodukt-Eigenschaften: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Grünere Alternativprodukt-Kategorie: Enabling,
• SMILES String: CC(C)(C)C(=O)O[Co-]1O[Co-](O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C)[O+]=C(O[Co-]2O[Co-](O\C(=[O+]\1)C(C)(C)C)\[O+]=C(\O[Co-](OC(=O)C(C)(C)C)\[O+]=C(\O[Co]OC(=[O+]2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/12C5H10O2.8Co.2O/c12*1-5(2,3)4(6)7;;;;;;;;;;/h12*1-3H3,(H,6,7);;;;;;;;;;/q;;;;;;;;;;;;4*+1;4*+2;;/p-12
• InChIKey: PBKALLJUIAKYSI-UHFFFAOYSA-B

Beschreibung

Allgemeine Beschreibung

Cobalt(II) oxo pivalate is a dinuclear complex that is typically formed by the direct reaction of cobalt carbonate with pivalic acid, followed by crystallization from MeCN. Its structure has two Co(II) sites bridged by two 2,11-carboxylates (Harris notation) and an oxygen atom.

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Anwendung

Synthesis of trinuclear complex [Co₃(Piv)₂L¹₂L²₂] by reacting cobalt(II)pivalate with spin labeled Schiff base has been reported in a study.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable