730459

(2S,2′S-(−)-[N,N′-Bis-(2-pyridylmethyl)]-2,2′-bipyrrolidin-bis-(acetonitril)-eisen(II)-hexafluoroantimonat

• Synonym(e): Eisen(II)-(S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)-pyrrolidin-2-yl]-pyrrolidin-1-yl}-methyl)-pyridin)-(bis-acetonitril), Fe(S,S-PDP), White-Chen Katalysator, [Fe(S,S-PDP)(CH₃CN)₂](SbF₆)₂
• Empirische Formel (Hill-System): C₂₄H₃₂F₁₂FeN₆Sb₂
• CAS-Nummer: 959395-10-9
• Molekulargewicht: 931.90
• MDL-Nummer: MFCD16038114
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329764568
• NACRES: NA.22

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Optische Aktivität: [α]20/D −30.0 to −20.0°, c = 0.2 in acetonitrile
• Eignung der Reaktion: core: iron; reagent type: catalyst; reaction type: C-H Activation
• mp (Schmelzpunkt): >300 °C
• SMILES String: [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4
• InChI: 1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1
• InChIKey: XUNWHBGEOCZDBX-QSKJABRXSA-B

Beschreibung

Anwendung

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Catalyst for:

• Oxidative radical reactions
• Selective oxidation of alkyl carbon-hydrogen bonds
• Methylene group oxidation

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable