726192

Bis-(4-methyl-phenyl)-iodonium-hexafluorophosphat

98%

• Synonym(e): Bis-(p-tolyl)-iodonium- hexafluorophosphat
• Empirische Formel (Hill-System): C₁₄H₁₄F₆IP
• CAS-Nummer: 60565-88-0
• Molekulargewicht: 454.13
• Beilstein: 3581445
• EG-Nummer: 262-301-5
• MDL-Nummer: MFCD06656584
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329764214
• NACRES: NA.23

Eigenschaften

• Assay: ≥97.5% (TLC); 98%
• Form: solid
• SMILES String: F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1
• InChI: 1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1
• InChIKey: LHLVGWWCRPPKBC-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Anwendung

• Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).


• Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).


• Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P280 - P305 + P351 + P338 - P310
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable