698555

1,1′-Bis-(dichlorphosphino)-ferrocen

≥96%

• Empirische Formel (Hill-System): C₁₀H₈Cl₄FeP₂
• CAS-Nummer: 142691-70-1
• Molekulargewicht: 387.78
• MDL-Nummer: MFCD01630854
• UNSPSC-Code: 12352101
• PubChem Substanz-ID: 329762010

Eigenschaften

• Assay: ≥96%
• Form: powder
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp (Schmelzpunkt): 67-71 °C
• Funktionelle Gruppe: phosphine
• SMILES String: [Fe].ClP(Cl)[C]1[CH][CH][CH][CH]1.ClP(Cl)[C]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H4Cl2P.Fe/c2*6-8(7)5-3-1-2-4-5;/h2*1-4H;
• InChIKey: CSJDQGIPHURAPH-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for synthesis of:

• Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
• Metallocene-bridged bisphosphaalkene

Catalyst for synthesis of oligonuclear heterometallic complexes

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P280 - P305 + P351 + P338 - P310
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges