578932

N-Allyl-N,N-bis(trimethylsilyl)amin

97%

• Synonym(e): (Prop-2-en-1-yl)bis(trimethylsilyl)amine, 1,1,1-Trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)silanamine, 3-Bis(trimethylsilyl)amino-1-propene, Bis(trimethylsilyl)allylamine, N,N-Bis(trimethylsilyl)-2-propen-1-amine, N,N-Bis(trimethylsilyl)allylamine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
• Lineare Formel: CH₂=CHCH₂NH[Si(CH₃)₃]₂
• CAS-Nummer: 7688-51-9
• Molekulargewicht: 201.46
• EG-Nummer: 231-699-2
• MDL-Nummer: MFCD00545193
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24880960
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.440 (lit.)
• bp: 72 °C/15 mmHg (lit.)
• Dichte: 0.816 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine
• SMILES String: C[Si](C)(C)N(CC=C)[Si](C)(C)C
• InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
• InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N

Beschreibung

Anwendung

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

• Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
• Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
• Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.

AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 109.0 °F - closed cup
• Flammpunkt (°C): 42.78 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter