482358

Ferroceniumtetrafluorborat

technical grade

• Synonym(e): Bis(cyclopentadienyl)iron tetrafluoroborate, Dicyclopentadienyliron fluoborate, Dicyclopentadienyliron tetrafluoroborate
• Empirische Formel (Hill-System): C₁₀H₁₀BF₄Fe
• CAS-Nummer: 1282-37-7
• Molekulargewicht: 272.84
• MDL-Nummer: MFCD00192174
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24871823
• NACRES: NA.22

Eigenschaften

• Qualität: technical grade
• Qualitätsniveau: 100
• Eignung der Reaktion: core: iron; reagent type: catalyst
• mp (Schmelzpunkt): 178 °C (dec.) (lit.)
• SMILES String: [Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1
• InChIKey: ZSPXIHLQPWVOQR-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Ferrocenium tetrafluoroborate [FeCp₂][BF₄] is one of the commonly employed ferrocenium salts within chemical synthesis. Ferrocenium salts are commonly used as Lewis acid catalysts, one-electron oxidants, and electron donors.[1]

Anwendung

Ferrocenium tetrafluoroborate serves as:

• an oxidizing agent in the synthesis of the monocationic Co(II)complex [CpCo(azpy)]⁺
• a Lewis acid catalyst in epoxide ring opening and to activatethe carbonyl group for addition or cycloadditions reactions
• an oxidizing agent when used in conjuntion with a Cl^-source[2]
• a reversible redox reagent between stannole dianion and bistannole-1,2-dianion[3]

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges