361755

(1,5-Cyclooctadien)-bis-(triphenylphosphin)-rhodium(I)-hexafluorophosphat Dichlormethan-Komplex (1:1)

• Synonym(e): NSC 179445
• Empirische Formel (Hill-System): C₄₅H₄₄Cl₂F₆P₃Rh
• CAS-Nummer: 35238-97-2
• Molekulargewicht: 965.55
• MDL-Nummer: MFCD02091684
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 24862254
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: core: rhodium; reagent type: catalyst
• mp (Schmelzpunkt): 215 °C (lit.)
• SMILES String: [Rh+].ClCCl.F[P-](F)(F)(F)(F)F.[CH]1[CH]CC[CH][CH]CC1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
• InChI: 1S/2C18H15P.C8H12.CH2Cl2.F6P.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;2-1-3;1-7(2,3,4,5)6;/h2*1-15H;1-2,7-8H,3-6H2;1H2;;/q;;;;-1;+1/b;;2-1-,8-7-;;;
• InChIKey: FCVRPQBVWYQXFH-ISVFTUMHSA-N

Beschreibung

Anwendung

Catalyst for:

• Polycyclotrimerization reactions
• Hydrosilylation and hydrogenation reactions
• Hydroformylation reactions
• Regioselective di- and trisilylation reactions
• Mannich and nitro-Mannich reactions
• Reductive alkylation reactions

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves