304026

Natriumcyclopentadienylid

2.4 M in THF

• Synonym(e): Cyclopentadienylnatrium -Lösung
• Empirische Formel (Hill-System): C₅H₅Na
• CAS-Nummer: 4984-82-1
• Molekulargewicht: 88.08
• Beilstein: 969542
• MDL-Nummer: MFCD00012161
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24858317
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 100
• Eignung der Reaktion: reagent type: ligand
• Konzentration: 2.4 M in THF
• Dichte: 0.938 g/mL at 25 °C
• SMILES String: [Na]C1C=CC=C1
• InChI: 1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H;
• InChIKey: PDTZVKVFAJGNRV-UHFFFAOYSA-N

Beschreibung

Anwendung

Useful reagent for the preparation of metallocenes and cyclopentadienyl metal complexes.

It can also be used in the synthesis of:

• Ruthenocene and fullerene molecular hybrid, Ru(η⁵- C₆₀Me₅)( η⁵-C₅H₅) (bucky ruthenocene).
• Allyl-substituted cyclopentadiene by palladium-catalyzed allylic alkylation.
• Bis(cyclopentadienyl)zirconium dichloride which is used as a catalyst in the synthesis of bis(indolyl)methanes and alkylation of heteroaryls.
• Cp-cobaltacycles from diphenylphosphinoalkynes and CoCl(PPh₃)₃.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H314,H335,H336,H351
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH018,EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter