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237965

Sigma-Aldrich

Lithiumfluorid

greener alternative

powder, -300 mesh

Synonym(e):

Fluorolithium

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100 G
CHF 45.90
1 KG
CHF 276.00

CHF 45.90


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100 G
CHF 45.90
1 KG
CHF 276.00

About This Item

Lineare Formel:
LiF
CAS-Nummer:
Molekulargewicht:
25.94
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

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Form

powder

Qualitätsniveau

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Partikelgröße

-300 mesh

mp (Schmelzpunkt)

845 °C (lit.)

Dichte

2.64 g/mL at 25 °C (lit.)

Grünere Alternativprodukt-Kategorie

SMILES String

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChIKey

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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Allgemeine Beschreibung

Lithium fluoride (LiF) is a highly versatile compound with a wide range of applications in research and development. Its unique physical and chemical properties make it suitable for use in optical components, battery technology, nuclear applications, ceramics, glasses, optoelectronics, metallurgy, thermoluminescent dosimeters, catalysis, environmental research, and biomedical applications.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Anwendung

Lithium Fluoride (LiF) can be used as an additive in electrolytes for lithium-ion batteries to enhance thermal stability and overall battery performance. Applied as a thin film on electrodes to improve their stability and lifespan by preventing degradation during cycling. LiF is a crucial component of the anode interface film due to its high-modulus shell, which can prevent LixSi pulverization, and its high chemical stability, which effectively suppresses side reactions at the interface. LiF is used in nuclear reactors and radiation detectors due to its low neutron cross-section and ability to capture neutrons, making it suitable for neutron shielding and detection.[1]

Lithium fluoride (LiF) can be used as a sintering aid that facilitates the etching of spinel particles for the degradation of magnesium aluminum spinel.[2] It can be used in the preparation of carbon-iron LiF nanocomposite based electrode materials for lithium-ion batteries.[3] It can also form thin interlayers on the counter electrode to enhance the fill factor and stabilize the high open-circuit voltages for polymer solar cells.[4]

Piktogramme

Exclamation mark

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Irrit. 2

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

A ferrocene-based carbon-iron lithium fluoride nanocomposite as a stable electrode material in lithium batteries
Prakash R, et al.
Journal of Materials Chemistry, 20(10), 1871-1876 (2010)
Degradation of magnesium aluminum spinel by lithium fluoride sintering aid
Villalobos GR, et al.
Journal of the American Ceramic Society. American Ceramic Society, 88(5), 1321-1322 (2005)
Effect of LiFmetal electrodes on the performance of plastic solar cells
Brabec CJ, et al.
Applied Physics Letters, 80(7), 1288-1290 (2002)
Fluorescent detection of single tracks of alpha particles using lithium fluoride crystals
Bilski P and Marczewska B
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms, 392, 41-45 (2017)
Asa Carlsson Tedgren et al.
Medical physics, 38(10), 5539-5550 (2011-10-14)
High energy photon beams are used in calibrating dosimeters for use in brachytherapy since absorbed dose to water can be determined accurately and with traceability to primary standards in such beams, using calibrated ion chambers and standard dosimetry protocols. For

Artikel

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. What is the purity?

    1 answer
    1. This product is not tested for purity. The testing includes the appearance, particle size, and identity confirmation by X-Ray Diffraction. Please see the link below to review a sample Certificate of Analysis: https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/237965-100G0000226203.pdf

      A highly purified version of the compound is available as product 449903. This material has a minimum purity specification of 99.99%. Please see the link below to review this product option:
      https://www.sigmaaldrich.com/product/aldrich/449903

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