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Trichloracetamid
99%
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About This Item
Lineare Formel:
Cl3CCONH2
CAS-Nummer:
Molekulargewicht:
162.40
Beilstein:
1754028
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
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Assay
99%
Form
solid
bp
238-240 °C (lit.)
mp (Schmelzpunkt)
139-141 °C (lit.)
SMILES String
NC(=O)C(Cl)(Cl)Cl
InChI
1S/C2H2Cl3NO/c3-2(4,5)1(6)7/h(H2,6,7)
InChIKey
UPQQXPKAYZYUKO-UHFFFAOYSA-N
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Allgemeine Beschreibung
Trichloroacetamide is the major degradation product of trichloroacetonitrile[1].
Anwendung
Trichloroacetamide was used in microarray-based transcriptomics and one-dimensional proton nuclear magnetic resonance based metabonomics to investigate the health effects of nitrogenous disinfection byproducts of trichloroacetamide in mice[2].
Signalwort
Warning
H-Sätze
P-Sätze
Gefahreneinstufungen
Eye Irrit. 2
Lagerklassenschlüssel
13 - Non Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Olaf R Ludek et al.
Carbohydrate research, 345(14), 2074-2078 (2010-08-10)
Obtaining high stereoselectivity in glycosylation reactions is often challenging in the absence of neighboring group participation. In this study, we demonstrate that activation of glycosyl trichloroacetimidate donors with immobilized perchloric acid on silica (HClO(4)-SiO(2)) provides higher alpha-selectivity than trimethylsilyl triflate
Joseph J Topczewski et al.
Journal of the American Chemical Society, 133(48), 19318-19321 (2011-11-09)
A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et(3)N·3HF reagent to provide branched allylic fluorides with complete regioselectivity. This
Jeffrey S Arnold et al.
Chemical communications (Cambridge, England), 48(94), 11531-11533 (2012-10-24)
We report the chiral diene ligated rhodium-catalyzed dynamic kinetic asymmetric transformation (DYKAT) of racemic secondary allylic trichloroacetimidates with a variety of N-methyl anilines, providing allylic N-methyl arylamines in high yields, regioselectivity, and enantiomeric excess. The rhodium-catalyzed DYKAT method addresses limitations
Peter J Meloncelli et al.
Carbohydrate research, 346(12), 1406-1426 (2011-05-03)
The ABO histo-blood group antigens are best known for their important roles in solid organ and bone marrow transplantation as well as transfusion medicine. Here we report the synthesis of the ABO type III and IV antigens with a 7-octen-1-yl
Tatsuya Komori et al.
Carbohydrate research, 344(12), 1453-1463 (2009-06-30)
A first systematic synthesis of the glycan parts of the a-series gangliosides (GT1a, GD1a, and GM1) utilizing the newly developed N-Troc-protected GM3 and galactosaminyl building blocks is described. The key processes, including the assembly of the GM2 sequence and its
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