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216607

Sigma-Aldrich

Bortrifluoriddiethyletherat

purified by redistillation, ≥46.5% BF3 basis

Synonym(e):

Bortrifluorid-ethyletherat

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4 X 25 ML
CHF 70.10
100 ML
CHF 73.80
800 ML
CHF 203.00

CHF 70.10

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4 X 25 ML
CHF 70.10
100 ML
CHF 73.80
800 ML
CHF 203.00

About This Item

Lineare Formel:
BF3 · O(C2H5)2
CAS-Nummer:
109-63-7
Molekulargewicht:
141.93
Beilstein:
3909607
EG-Nummer:
203-689-8
MDL-Nummer:
MFCD00013194
UNSPSC-Code:
12352106
PubChem Substanz-ID:
57647937
NACRES:
NA.22

CHF 70.10

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Dampfdichte

4.9 (vs air)

Dampfdruck

4.2 mmHg ( 20 °C)

Form

liquid

Aufgereinigt durch

redistillation

Expl.-Gr.

36 %

Konzentration

≥46.5% boron trifluoride

Brechungsindex

n20/D 1.344 (lit.)

bp

126-129 °C (lit.)

mp (Schmelzpunkt)

−58 °C (lit.)

Dichte

1.15 g/mL (lit.)

Funktionelle Gruppe

ether

Lagertemp.

2-8°C

SMILES String

CC[O+](CC)[B-](F)(F)F

InChI

1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3

InChIKey

MZTVMRUDEFSYGQ-UHFFFAOYSA-N

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Anwendung

Katalysator bei der Synthese von Polyolketten.[1] Reagenz für die Kupplung von Iminen mit Allylstannanen[2] und von 4′-nitrobenzolsulfenanilid mit Alkenen und Alkinen.[3]

Verpackung

Die 25-mL-Sure/Seal™-Flasche wird für den Einmalgebrauch empfohlen. Wiederholte Einstiche führen höchstwahrscheinlich zu einer Leistungsminderung des Produkts.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation

Zielorgane

Kidney

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

137.3 °F - closed cup

Flammpunkt (°C)

58.5 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
MKCW0188
MKCS2430
MKCR2398
MKCQ9916
SHBN1593

Die passende Version wird nicht angezeigt?

Wenn Sie eine bestimmte Version benötigen, können Sie anhand der Lot- oder Chargennummer nach einem spezifischen Zertifikat suchen.

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Tetrahedron, 50, 12395-12395 (1994)
The Journal of Organic Chemistry, 54, 4739-4739 (1989)
The Journal of Organic Chemistry, 54, 4982-4982 (1989)
George R Pettit et al.
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Questions

1–4 of 4 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  4. What is the "acidic gas" referred to in the statement "Water hydrolyzes material liberating acidic gas..." in the MSDS for Product 216607, Boron trifluoride diethyl etherate?

    1 answer

    1. The gas in question is hydrogen fluoride, which is toxic.

      Helpful?

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