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Dokumente

122793

Sigma-Aldrich

3-Butensäurenitril

98%

Synonym(e):

Allylcyanid, Vinylacetonitril

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About This Item

Lineare Formel:
CH2=CHCH2CN
CAS-Nummer:
109-75-1
Molekulargewicht:
67.09
Beilstein:
605352
EG-Nummer:
203-701-1
MDL-Nummer:
MFCD00001962
UNSPSC-Code:
12162002
PubChem Substanz-ID:
24847509
NACRES:
NA.23

Assay

98%

Selbstzündungstemp.

851 °F

Brechungsindex

n20/D 1.405 (lit.)

bp

116-121 °C (lit.)

Dichte

0.834 g/mL at 25 °C (lit.)

SMILES String

C=CCC#N

InChI

1S/C4H5N/c1-2-3-4-5/h2H,1,3H2

InChIKey

SJNALLRHIVGIBI-UHFFFAOYSA-N

Piktogramme

FlameSkull and crossbones
GHS02,GHS06

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

75.2 °F - closed cup

Flammpunkt (°C)

24 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Allylchlorid reagent grade, 98%

Sigma-Aldrich

A30702

Allylchlorid

Acrylnitril analytical standard

Supelco

31564

Acrylnitril

Propionitril 99%

Sigma-Aldrich

185590

Propionitril

Katja Witzel et al.
PloS one, 8(9), e71877-e71877 (2013-09-17)
The soil-borne fungal pathogen Verticillium longisporum is able to penetrate the root of a number of plant species and spread systemically via the xylem. Fumigation of Verticillium contaminated soil with Brassica green manure is used as an environmentally friendly method
Ryo Yazaki et al.
Journal of the American Chemical Society, 132(15), 5522-5531 (2010-03-27)
We report that a hard Lewis base substantially affects the reaction efficiency of direct catalytic asymmetric gamma-addition of allyl cyanide (1a) to ketones promoted by a soft Lewis acid/hard Brønsted base catalyst. Mechanistic studies have revealed that Cu/(R,R)-Ph-BPE and Li(OC(6)H(4)-p-OMe)
E Balbuena et al.
Brain research, 904(2), 298-306 (2001-06-19)
Animals exposed to allylnitrile develop permanent abnormalities in motor behaviour, similar to those caused by 3,3'-iminodipropionitrile (IDPN) and crotononitrile. IDPN and crotononitrile effects have been attributed to vestibular hair cell degeneration, but allylnitrile has been suggested to modify behaviour through
Asymmetric synthesis of isothiazoles through Cu catalysis: direct catalytic asymmetric conjugate addition of allyl cyanide to α,β-unsaturated thioamides.
Yuka Yanagida et al.
Angewandte Chemie (International ed. in English), 50(34), 7910-7914 (2011-07-07)
D-L Cheng et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 42(3), 351-357 (2004-02-12)
Three strains of Bifidobacterium sp., B. pseudocatenulatum, B. adolescentis, and B. longum were studied for their ability to digest glucosinolates, sinigrin (SNG) and glucotropaeolin (GTL), in vitro. All strains digested both glucosinolates during 24-48 h cultivation, accompanied by a decline
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