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Sigma-Aldrich

Zinc trifluoromethanesulfonate

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98%

Synonyme(s) :

Bis(trifluoromethanesulfonato)zinc, Zinc trifluoromethylsulfonate, Zn(OTf)2, Trifluoromethanesulfonic acid zinc salt, Zinc triflate, Zn(OTf)2

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10 G
86,50 $
50 G
347,00 $
200 G
1 080,00 $

86,50 $


Disponible pour expédition le22 avril 2025Détails


Devis pour commande en gros

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10 G
86,50 $
50 G
347,00 $
200 G
1 080,00 $

About This Item

Formule linéaire :
(CF3SO3)2Zn
Numéro CAS:
Poids moléculaire :
363.53
Beilstein:
4028195
Numéro CE :
Numéro MDL:
Code UNSPSC :
12161600
ID de substance PubChem :
Nomenclature NACRES :
NA.22

86,50 $


Disponible pour expédition le22 avril 2025Détails


Devis pour commande en gros

Niveau de qualité

Essai

98%

Pertinence de la réaction

core: zinc
reagent type: catalyst

Caractéristiques du produit alternatif plus écologique

Catalysis
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≥300 °C (lit.)

Autre catégorie plus écologique

Chaîne SMILES 

[Zn++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

Clé InChI

CITILBVTAYEWKR-UHFFFAOYSA-L

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Description générale

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Zinc trifluoromethanesulfonate acts as a lewis acid in nucleophilic addition and as a catalyst in aldol reactions.[1]

Application

  • Initiating a high-temperature zinc ion battery through a triazolium-based ionic liquid: This study explores the use of zinc trifluoromethanesulfonic acid in ionic liquid for high-temperature zinc ion batteries, demonstrating significant improvements in conductivity and stability. (Li et al., 2022).
  • Enhancing the solubility of 6-mercaptopurine by formation of ionic cocrystal with zinc trifluoromethanesulfonate: The research focuses on improving the solubility of 6-mercaptopurine by forming ionic cocrystals with zinc trifluoromethanesulfonate, resulting in single-crystal-to-single-crystal transformation. (Yao et al., 2014).
  • Spontaneous desaturation of the solvation sheath for high-performance anti-freezing zinc-ion gel-electrolyte: This paper discusses the development of a high-performance anti-freezing zinc-ion gel-electrolyte using zinc trifluoromethanesulfonate, which shows excellent performance even at low temperatures. (Li et al., 2023).

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Consulter la Bibliothèque de documents

Novel heterogeneous zinc triflate catalysts for the rearrangement of ?-pinene oxide.
Wilson K, et al.
Catalysis Letters, 61(1-2), 51-55 (1999)
Regioselective synthesis of 3-alkylindoles mediated by zinc triflate.
Zhu X and Ganesan A
The Journal of Organic Chemistry, 67(8), 2705-2708 (2002)
Zinc triflate as Lewis acid in nucleophilic addition to cyclic N-acyliminium ions
Ronaldo Aloise P et al.
Synlett, 2005, 2297-2300 (2005)
Magnesium and zinc-catalyzed thioketalization
Corey EJ and Shimoji K
Tetrahedron Letters, 24, 169-169 (1983)
B V Subba Reddy et al.
Organic letters, 15(3), 464-467 (2013-01-18)
A novel method has been devised for the synthesis of 2,4,5-trisubstituted pyrrole derivatives through the coupling of α-diazoketones with β-enaminoketones and esters using 10 mol % of Cu(OTf)(2). A wide range of 2,3-disubstituted indole derivatives were also prepared from α-diazoketones

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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