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Sigma-Aldrich

Aluminum-nickel alloy

purum, 50% Al basis, 50% Ni basis

Sinônimo(s):

Nickel-aluminum alloy, Raney®-Nickel alloy

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100 G
R$ 903,00
500 G
R$ 2.333,00

About This Item

Número CAS:
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

R$ 903,00


Disponível para enviar em02 de abril de 2025Detalhes


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Nível de qualidade

grau

purum

Formulário

powder

composição

Al, 50%
Ni, 50%

adequação da reação

core: nickel
reagent type: catalyst

cadeia de caracteres SMILES

[Al].[Ni]

InChI

1S/Al.Ni

chave InChI

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Aplicação

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.[1]
  • For the conversion of carbonyl compounds to hydrocarbons.[2]
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.[1]
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.[3][4]
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.[5]
  • For the synthesis of alloyed skeletal Ni catalysts.[6]

Informações legais

Raney is a registered trademark of W.R. Grace & Co.-Conn.

substituído por

Nº do produto
Descrição
Preços

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Código de classe de armazenamento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Visite a Biblioteca de Documentos

Reduction of carbonyl groups to the corresponding methylenes with Ni-Al alloy in water.
Ishimoto K, et al.
Chemical Communications (Cambridge, England), 89(4), 514-515 (2003)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)

Artigos

Mechanical alloying is a “brute force” method of affecting alloying and chemical reactions. The mixture of reactant powders and several balls are placed in the milling jar of a high-energy ball mill, for example, a shaker mill or a planetary mill.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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