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33801

Sigma-Aldrich

L-(+)-Tartaric acid

puriss. p.a., reag. ISO, 99.5-101.0% (calc. to the dried substance)

Sinônimo(s):

(2R,3R)-(+)-Tartaric acid, L-Threaric acid

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About This Item

Fórmula linear:
HO2CCH(OH)CH(OH)CO2H
Número CAS:
Peso molecular:
150.09
Beilstein:
1725147
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.21

Agency

Ph. Eur.
USP/NF
reag. ISO

Nível de qualidade

densidade de vapor

5.18 (vs air)

grau

puriss. p.a.

Ensaio

99.5-101.0% (calc. to the dried substance)

forma

powder or crystals

atividade óptica

[α]20/D +12.0 to +12.8°, c = 20% in H2O

temperatura de autoignição

797 °F

Impurezas

≤0.0005% heavy metals (as Pb)

resíduo de ignição

≤0.1% (as SO4)

perda

≤0.1% loss on drying, 105 °C

pf

170-172 °C (lit.)

traços de ânion

chloride (Cl-): ≤5 mg/kg
phosphate (PO43-): ≤10 mg/kg
sulfate (SO42-): ≤150 mg/kg

traços de cátion

Ca: ≤20 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Pb: ≤2 mg/kg
Zn: ≤5 mg/kg

cadeia de caracteres SMILES

O[C@H]([C@@H](O)C(O)=O)C(O)=O

InChI

1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m1/s1

chave InChI

FEWJPZIEWOKRBE-JCYAYHJZSA-N

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Descrição geral

L-(+)-Tartaric acid is an organic acid naturally found in grapes and wines. It is widely used as flavoring agent and antioxidizing agent for various beverages (grape juices and wines). It can be synthesized starting from L-ascorbic acid (AA, vitamin C). Its forms various hydrogen-L-tartrate salts, which have important applications in crystal engineering studies. Its quantification in grape juice has been carried out by recording HPLC chromatograms.

Aplicação

L-(+)-Tartaric acid may be employed as starting reagent in the synthesis of enantiomeric forms of pyrrolidinoisoquinoline derivatives.

Pictogramas

Corrosion

Palavra indicadora

Danger

Frases de perigo

Declarações de precaução

Classificações de perigo

Eye Dam. 1

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

302.0 °F - closed cup

Ponto de fulgor (°C)

150 °C - closed cup

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves


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Organic salts of L-tartaric acid: materials for second harmonic generation with a crystal structure governed by an anionic hydrogen-bonded network.
Aakeroy CB, et al.
Journal of the Chemical Society. Chemical Communications, 7, 553-555 (1992)
Asymmetric synthesis of both enantiomers of pyrrolidinoisoquinoline derivatives from L-malic acid and L-tartaric acid.
Lee YS, et al.
The Journal of Organic Chemistry, 60(22), 7149-7152 (1955)
Seth DeBolt et al.
Proceedings of the National Academy of Sciences of the United States of America, 103(14), 5608-5613 (2006-03-29)
The biosynthetic pathway of L-tartaric acid, the form most commonly encountered in nature, and its catabolic ties to vitamin C, remain a challenge to plant scientists. Vitamin C and L-tartaric acid are plant-derived metabolites with intrinsic human value. In contrast
Organic acid profile of Turkish white grapes and grape juices.
Soyer Y, et al.
J. Food Compos. Anal., 16(5), 629-636 (2003)
J B Olivato et al.
Carbohydrate polymers, 92(2), 1705-1710 (2013-02-13)
Tartaric acid (TA), a dicarboxylic acid, can act as a compatibiliser in starch/polyester blends. A mixture design was proposed to evaluate the effect of TA on the properties of starch/poly (butylene adipate co-terephthalate) (PBAT) blown films plasticised with glycerol. The

Protocolos

Silica gel G 254 plates are suitable for analysis of Dextromethorphan following the European pharmacopeia monograph.

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