Pular para o conteúdo
Merck
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Documentos

30-1220

Sigma-Aldrich

N,N,N′,N′-tetrametiletilenodiamina

≥99.0%

Sinônimo(s):

1,2-Bis(dimetilamino)etano, TEMED, TMEDA

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About This Item

Fórmula linear:
(CH3)2NCH2CH2N(CH3)2
Número CAS:
Peso molecular:
116.20
Beilstein:
1732991
Número CE:
Número MDL:
Código UNSPSC:
12352116
ID de substância PubChem:

Ensaio

≥99.0%

forma

liquid

Lim. expl.

9.08 %

disponibilidade

available only in Japan

índice de refração

n20/D 1.4179 (lit.)

pb

120-122 °C (lit.)

pf

−55 °C (lit.)

densidade

0.775 g/mL at 20 °C (lit.)

cadeia de caracteres SMILES

CN(C)CCN(C)C

InChI

1S/C6H16N2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3

chave InChI

KWYHDKDOAIKMQN-UHFFFAOYSA-N

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Adequação

for electrophoresis

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

61.7 °F - closed cup

Ponto de fulgor (°C)

16.5 °C - closed cup


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Xin Ku et al.
Journal of combinatorial chemistry, 11(3), 338-340 (2009-03-06)
A practical and promising protocol was developed for S-arylations of various thiols with different substituted aryl halides. The reactions were readily facilitated to afford desired thioethers under mild conditions in good to excellent yields. The versatility, air-stability, operational simplicity of
Andrew J Ross et al.
The Journal of organic chemistry, 76(6), 1727-1734 (2011-02-16)
The structure of the alkylzinc-tetramethylethyl-enediamine (TMEDA) cluster cation 3 has been determined in the gas phase by a combination of tandem mass spectrometry, infrared multiphoton dissociation (IRMPD) spectroscopy, and DFT calculations. Both sets of experimental results establish the existence of
Kazuhiro Uehara et al.
Inorganic chemistry, 49(4), 2008-2015 (2010-01-26)
Reactions of (en*)Pd(NO(3))(2) (en* = N,N,N',N'-tetramethylethylenediamine)with a series of organic bridging ligands of pyrazine, 1,2-bis(4-pyridyl)ethylene, 1,2-bis(4-pyridyl)acetylene, and 1,4-bis(4-pyridyl)benzene are carried out to investigate factors controlling the supramolecular structures and the equilibrium between the molecular triangles and the squares in solutions.
Kiyohito Shimura
Electrophoresis, 30(1), 11-28 (2008-12-25)
The methodological advancements in CIEF in tubes and microchips during the period between 2002 and early 2008 are reviewed as a continuation of previous review by the same author (Electrophoresis 2002, 23, 3847-3857). After a brief introduction, the following topics
Jack K Clegg et al.
Dalton transactions (Cambridge, England : 2003), 39(11), 2804-2815 (2010-03-05)
New examples of nitrogen base adducts of dinuclear Co(II), Ni(II) and Cu(II) complexes of the doubly deprotonated forms of 1,3-aryl linked bis-beta-diketones of type [RC(=O)CH(2)C(=O)C(6)H(4)C(=O)CH(2)C(=O)R] (L(1)H(2)) incorporating the mono- and difunctional amine bases pyridine (Py), 4-ethylpyridine (EtPy), piperidine (pipi), 1,4-piperazine

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