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Sigma-Aldrich

Molybdenum tris(1,2-bis(trifluoromethyl)ethane-1,2-dithiolene)

Sinônimo(s):

Mo(tfd)3

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About This Item

Fórmula empírica (Notação de Hill):
C12F18MoS6
Número CAS:
1494-07-1
Peso molecular:
774.43
Código UNSPSC:
12352103
ID de substância PubChem:
329768505

Formulário

solid

cadeia de caracteres SMILES

FC(F)(F)C(S1)=C(C(F)(F)F)S[Mo]213(SC(C(F)(F)F)=C(C(F)(F)F)S3)SC(C(F)(F)F)=C(C(F)(F)F)S2

InChI

1S/3C4H2F6S2.Mo/c3*5-3(6,7)1(11)2(12)4(8,9)10;/h3*11-12H;/q;;;+6/p-6/b3*2-1-;

chave InChI

KPELOYUGUICPOT-JVUUZWNBSA-H

Descrição geral

The p dopant Mo(tfd)3 has high electron affinity (EA= 5.6 eV).[1][2]The efficiency of Mo(tfd)3 as a dopant has been studied extensively by ultraviolet and X ray photoelectron spectroscopy, Rutherford backscattering, etc. [3]

Aplicação

Molybdenum tris(1,2-bis(trifluoromethyl)ethane-1,2-dithiolene) (Mo(tfd)3) may be used to p dope the hole transporting layer of HTM N,N′-di[(1-naphthyl)-N,N′-diphenyl]-1,1′-biphenyl-4,4′- diamine. [1]
It may be used as a dopant to reduced contact resistance in pentacene based organic field effect transistors (OFETs). [4]

Ações bioquímicas/fisiológicas

p-dopant

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Lot/Batch Number

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A molybdenum dithiolene complex as p-dopant for hole-transport materials: A multitechnique experimental and theoretical investigation.
Qi Y, et al.
Chemistry of Materials, 524-531 null
Pentacene organic field-effect transistors with doped electrode-semiconductor contacts
Tiwari SP, et al.
Organic Electronics null
A Molybdenum Dithiolene Complex as p-Dopant for Hole-Transport Materials: A Multitechnique Experimental and Theoretical Investigation
Qi, Y.;
Chemistry of Materials, 22, 524-524 (2010)
Yabing Qi et al.
Journal of the American Chemical Society, 131(35), 12530-12531 (2009-08-15)
Experimental and theoretical results are presented on the electronic structure of molybdenum tris[1,2-bis(trifluoromethyl) ethane-1,2-dithiolene] (Mo(tfd)(3)), a high electron-affinity organometallic complex that constitutes a promising candidate as a p-dopant for organic molecular semiconductors. The electron affinity of the compound, determined via
Use of a high electron-affinity molybdenum dithiolene complex to p-dope hole-transport layers.
Qi Y, et al.
Journal of the American Chemical Society, 12530-12531 null
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