662283

Bis(tert-butylcarbonyloxy)iodobenzene

97%

• Sinônimo(s): (Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene
• Fórmula empírica (Notação de Hill): C₁₆H₂₃IO₄
• Número CAS: 57357-20-7
• Peso molecular: 406.26
• Número MDL: MFCD08276835
• Código UNSPSC: 12352002
• ID de substância PubChem: 24884583
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: 97%
• Formulário: solid
• adequação da reação: reagent type: catalyst; reaction type: C-H Activation; reagent type: oxidant
• pf: 104-109 °C
• grupo funcional: iodo
• cadeia de caracteres SMILES: CC(C)(C)C(=O)O[I](OC(=O)C(C)(C)C)c1ccccc1
• InChI: 1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
• chave InChI: DZKPLZUSZXYHFB-UHFFFAOYSA-N

Descrição

Aplicação

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Reagent for:

• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
• Palladium-catalyzed diamination
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
• C-H acyloxylation of arenes

• Hypervalent iodine oxidant

Hypervalent iodine reagent used with the Rh₂(esp)₂ catalyst (662623) in the amination of C-H bonds.[1]

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)