661023

Hydroxy(cyclooctadiene)rhodium(I) dimer

95%

• Sinônimo(s): (Cyclooctadiene)rhodium hydroxide dimer, 1,5-Cyclooctadiene)hydroxyrhodium dimer, Bis(cyclooctadiene)dihydroxodirhodium, Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di--μ-hydroxydirhodium, Bis[(1,5-cyclooctadiene)(hydroxy)rhodium], [Rh(OH)(1,5-cod)]₂
• Fórmula empírica (Notação de Hill): C₁₆H₂₆O₂Rh₂
• Número CAS: 73468-85-6
• Peso molecular: 456.19
• Número MDL: MFCD08457638
• Código UNSPSC: 12161600
• ID de substância PubChem: 24884496
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: 95%
• Formulário: solid
• adequação da reação: core: rhodium; reagent type: catalyst
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pf: 199 °C (dec.)
• categoria alternativa mais ecológica: Aligned,
• cadeia de caracteres SMILES: O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• chave InChI: IUAQXTGDGDIMOD-MIXQCLKLSA-L

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Rhodium catalyst employed with R-BINAP or R-SEGPHOS^® ligands in a synthesis of chiral 3,3-disubstituted-1-indanones.[1]

Informações legais

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)