403547

3,6-Di-2-pyridyl-1,2,4,5-tetrazine

96%

• Fórmula empírica (Notação de Hill): C₁₂H₈N₆
• Número CAS: 1671-87-0
• Peso molecular: 236.23
• Número MDL: MFCD00121717
• Código UNSPSC: 12352100
• ID de substância PubChem: 24865200
• NACRES: NA.22

Propriedades

• Ensaio: 96%
• forma: solid
• pf: 225 °C (dec.) (lit.)
• cadeia de caracteres SMILES: c1ccc(nc1)-c2nnc(nn2)-c3ccccn3
• InChI: 1S/C12H8N6/c1-3-7-13-9(5-1)11-15-17-12(18-16-11)10-6-2-4-8-14-10/h1-8H
• chave InChI: JFBIRMIEJBPDTQ-UHFFFAOYSA-N

Descrição

Descrição geral

3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) undergoes solvothermal reaction with CuSO₄.6H₂O and Cu(Ac)₂.H₂O to afford copper containing coordination polymers. It reacts with enamine derivative of morpholine and 5-,6-,7- and 8-membered cyclic ketones to afford pyridazine derivatives.

3,6-Di-2-pyridyl-1,2,4,5-tetrazine undergoes solid-state reaction with fullerene C₆₀ by high-speed vibration milling technique. It acts as electron-deficient diene in the inverse electron demand Diels Alder reaction.

Aplicação

3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies:

• Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis.
• Synthesis of novel cyclic tetranuclear Zn^II complex.
• Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves