332364

Allyltriphenylstannane

97%

• Sinônimo(s): 2-Propenyl-triphenylstannane, Allyltriphenyltin
• Fórmula linear: CH₂=CHCH₂Sn(C₆H₅)₃
• Número CAS: 76-63-1
• Peso molecular: 391.09
• Beilstein: 3612762
• Número CE: 200-975-4
• Número MDL: MFCD00048162
• Código UNSPSC: 12352103
• ID de substância PubChem: 24859890
• NACRES: NA.22

Propriedades

• Ensaio: 97%
• Formulário: solid
• pf: 71-74 °C (lit.)
• cadeia de caracteres SMILES: C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
• chave InChI: NDUYAGLANMHJHF-UHFFFAOYSA-N

Descrição

Descrição geral

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.[1]

Aplicação

Allyltriphenylstannane can be used:

• As a reagent in the C-H phenylation of azoles catalyzed by palladium.[2]
• As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)₃.[3]
• As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.[4]

Informações de segurança

• Pictogramas: GHS06,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H301 + H311 + H331,H410
• Declarações de precaução: P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Classificações de perigo: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Código de classe de armazenamento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)