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Documentos

307882

Sigma-Aldrich

(R)-(−)-2-Phenylglycine methyl ester hydrochloride

≥95%

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About This Item

Fórmula linear:
C6H5CH(NH2)CO2CH3·HCl
Número CAS:
19883-41-1
Peso molecular:
201.65
Número CE:
243-399-9
Número MDL:
MFCD00137487
Código UNSPSC:
12352200
eCl@ss:
32160406
ID de substância PubChem:
24858635
NACRES:
NA.22

Ensaio

≥95%

forma

solid

atividade óptica

[α]20/D −118°, c = 1 in H2O

adequação da reação

reaction type: solution phase peptide synthesis

pf

189-191 °C (lit.)

aplicação(ões)

peptide synthesis

cadeia de caracteres SMILES

Cl.COC(=O)[C@H](N)c1ccccc1

InChI

1S/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m1./s1

chave InChI

DTHMTBUWTGVEFG-DDWIOCJRSA-N

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H319

Declarações de precaução

P305 + P351 + P338

Classificações de perigo

Eye Irrit. 2

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análise (COA)

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Penicillin Amidase from Escherichia coli 5-10 units/mg protein

Sigma-Aldrich

76427

Penicillin Amidase from Escherichia coli

K Sasaki et al.
Bioscience, biotechnology, and biochemistry, 61(10), 1783-1785 (1997-11-15)
The absolute configuration of pectenotoxin-6 (4, PTX6), found in association with diarrhetic shellfish poisoning, was identified by NMR spectroscopy using a chiral anisotropic reagent, phenylglycine methyl ester (PGME), which was condensed with a carboxyl group of 4.
Sixto Malato et al.
Journal of hazardous materials, 146(3), 440-446 (2007-05-29)
This paper reports on the combined solar photo-Fenton/biological treatment of an industrial effluent (initial total organic carbon, TOC, around 500mgL(-1)) containing a non-biodegradable organic substance (alpha-methylphenylglycine at 500mgL(-1)), focusing on pilot plant tests performed for design of an industrial plant
M I Youshko et al.
Biochemistry. Biokhimiia, 65(12), 1367-1375 (2001-02-15)
Kinetic regularities of the enzymatic acyl group transfer reactions have been studied using ampicillin synthesis catalyzed by E. coli penicillin acylase as an example. It was shown that ampicillin synthesis proceeds through the formation of an acylenzyme-nucleophile complex capable of
P S Nys et al.
Antibiotiki, 26(12), 920-932 (1981-12-01)
The possible use of various procedures for estimation of the ionization constants of the Michaelis complex by the pH dependence of the maximum enzymatic reaction rate is discussed. It is shown that the procedures described in the literature for estimation
Esther M Gabor et al.
Protein engineering, design & selection : PEDS, 17(7), 571-579 (2004-08-31)
A semi-random mutagenesis approach was followed to increase the performance of penicillin acylase PAS2 in the kinetically controlled synthesis of ampicillin from 6-aminopenicillanic acid (6-APA) and activated D-phenylglycine derivatives. We directed changes in amino acid residues to positions close to
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