26235

2-(3-Chloropropyl)-1,3-dioxolane

≥97.0% (GC)

• Sinônimo(s): 4-Chlorobutyraldehyde ethylene acetal
• Fórmula empírica (Notação de Hill): C₆H₁₁ClO₂
• Número CAS: 16686-11-6
• Peso molecular: 150.60
• Beilstein: 1236588
• Número MDL: MFCD00043135
• Código UNSPSC: 12352100
• ID de substância PubChem: 57648166
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥97.0% (GC)
• Formulário: liquid
• índice de refração: n20/D 1.453
• p.e.: 93-94 °C/12 mmHg (lit.)
• densidade: 1.142 g/mL at 20 °C (lit.)
• grupo funcional: chloro; ether
• cadeia de caracteres SMILES: ClCCCC1OCCO1
• InChI: 1S/C6H11ClO2/c7-3-1-2-6-8-4-5-9-6/h6H,1-5H2
• chave InChI: ZBPUNVFDQXYNDY-UHFFFAOYSA-N

Descrição

Aplicação

2-(3-Chloropropyl)-1,3-dioxolane (2-(3′-chloropropyl)-1,3-dioxolane) is a masked γ-chlorobutyraldehyde and was used for the introduction of 3-(1,3-dioxolan-2-yl)propyl moiety[1][2][3]. It was also used in the synthesis of:

• (±)-histrionicotoxin and (±)-histrionicotoxin 235A using a two-directional strategy[4]
• 4-iodobutyraldehyde, 5-iodovaleraldehyde and 5-iodo-2-petanone[5]
• corresponding phosphonate[6]

Outras notas

Masked γ-chlorobutyraldehyde, useful for the introduction of the 3-(1,3-dioxolan-2-yl)propyl moiety[1][2][3]; Preparation and use of the corresponding phosphonate[6]

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 174.2 °F - closed cup
• Ponto de fulgor (°C): 79 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves, type ABEK (EN14387) respirator filter