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Sigma-Aldrich

Copper(I) bromide

99.999% trace metals basis

Sinônimo(s):

Cuprous bromide

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About This Item

Fórmula linear:
CuBr
Número CAS:
Peso molecular:
143.45
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

Ensaio

99.999% trace metals basis

forma

powder

adequação da reação

reagent type: catalyst
core: copper

Impurezas

≤15.0 ppm Trace Metal Analysis

pf

504 °C (lit.)

densidade

4.71 g/mL at 25 °C (lit.)

aplicação(ões)

battery manufacturing

cadeia de caracteres SMILES

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

chave InChI

NKNDPYCGAZPOFS-UHFFFAOYSA-M

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Descrição geral

Copper(I) bromide is a faint green inorganic diamagnetic solid that has a polymeric structure like zinc sulfide. It is insoluble in water and widely used in the field of catalysis, nanomaterial synthesis, and solar cells.

Aplicação

Copper(I) bromide can be used:
  • As a solution-processable hole transport layer (HTL) for organic solar cells (OSCs). CuBr enhances the power conversion efficiency of solar cells.
  • As a precursor to synthesize photoluminescent metal organic frameworks(MOFs).
  • To synthesize highly emissive three-coordinate copper(I) complexes as a dopant in OLEDs with maximum external quantum efficiency of 21.3%.
  • As a catalyst with ligands for atom transfer radical polymerization (ATRP) reaction of tertiary alkyl halides in 14 different solvents to determine the rate constant.
  • To synthesize macrocyclic polymer via intramolecular radical trap-assisted atom transfer radical coupling.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


Certificados de análise (COA)

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An acs-Type Metal--Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
Sheng Hu, et al.
European Journal of Inorganic Chemistry, 2012, 3669-3673 (2012)
Copper Bromide as an Efficient Solution-Processable Hole Transport Layer for Organic Solar Cells: Effect of Solvents
Ranoo Bhargav, et al.
ACS Omega, 4, 6028-6034 (2019)
Carla Sardo et al.
International journal of pharmaceutics, 563, 347-357 (2019-04-03)
Sustained pulmonary delivery of tobramycin from microparticles composed of drug/polymer nanocomplexes offers several advantages against traditional delivery methods. Namely, in patients with cystic fibrosis, microparticle delivery can protect the tobramycin being delivered from strong mucoadhesive interactions, thus avoiding effects on
Denissova I and Barriault L et al.
Handbook of Reagents for Organic Synthesis null
Highly Efficient Green Organic Light-Emitting Diodes Containing Luminescent Three-Coordinate Copper(I) Complexes
Masashi Hashimoto, et al.
Journal of the American Chemical Society, 133, 10348-10351 (2011)

Artigos

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocolos

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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