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Documentos Principais

E14403

Sigma-Aldrich

Ethyl α-bromoisobutyrate

98%

Sinônimo(s):

Ethyl 2-bromo-2-methylpropionate

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About This Item

Fórmula linear:
(CH3)2CBrCOOC2H5
Número CAS:
Peso molecular:
195.05
Beilstein:
1098947
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Formulário:
liquid
Ensaio:
98%

Nível de qualidade

Ensaio

98%

Formulário

liquid

índice de refração

n20/D 1.444 (lit.)

p.e.

65-67 °C/11 mmHg (lit.)

densidade

1.329 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CCOC(=O)C(C)(C)Br

InChI

1S/C6H11BrO2/c1-4-9-5(8)6(2,3)7/h4H2,1-3H3

chave InChI

IOLQWGVDEFWYNP-UHFFFAOYSA-N

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Descrição geral

Ethyl α-bromoisobutyrate is an organic bromoester used as an initiator in controlled radical polymerization reactions.

Aplicação

Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

140.0 °F - closed cup

Ponto de fulgor (°C)

60 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Na Wang et al.
Analytical methods : advancing methods and applications, 12(36), 4438-4446 (2020-08-29)
As robust functional polymers, polymer brush-based hybrid nanomaterials have potential application in the highly sensitive determination of tumor markers (TMs). Currently, there are plentiful reports on the polymerization methods of functional polymer brushes. Low ppm ATRP (activators (re)generated by electron
Katarzyna Niesyto et al.
International journal of molecular sciences, 22(1) (2021-01-06)
In this study, drug nanocarriers were designed using linear copolymers with different contents of cholinium-based ionic liquid units, i.e., [2-(methacryloyloxy)ethyl]trimethylammonium chloride (TMAMA/Cl: 25, 50, and 75 mol%). The amphiphilicity of the copolymers was evaluated on the basis of their critical
Dongpo Xu et al.
Analytical and bioanalytical chemistry, 412(30), 8371-8378 (2020-10-04)
In this study, a simple and efficient strategy for the construction of hydrangea-like mesoporous WO3 nanoflowers templated using diblock copolymer PS119-PtBA129 was developed. The nanoflower shows good gas sensing properties, especially for 3-hydroxy-2-butanone (3H-2B), which is the signature metabolite of
Hailing He et al.
Materials (Basel, Switzerland), 12(16) (2019-08-10)
The balance of strengthening and toughening of poly (lactic acid) (PLA) has been an intractable challenge of PLA nanocomposite development for many years. In this paper, core-shell nanoparticles consisting of a silica rigid core and poly (butyl acrylate) (PBA) flexible
Wojciech Raj et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-21)
A totally new approach in the synthesis of mixed polymer brushes tethered on polyamide (PA) surfaces is presented herein. As a proof of concept, two types of homopolymers were synthesized in sequential surface-initiated atom transfer radical polymerization (SI-ATRP) reactions: poly(methyl

Artigos

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Protocolos

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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