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247197

Sigma-Aldrich

Methyl vinyl sulfone

≥97%

Sinônimo(s):

(Methylsulfonyl)ethene, 1-Methylsulfonylethene, 1-Methylsulfonylethylene, Methanesulfonylethene, Methyl vinyl sulphone, Vinyl methyl sulfone

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About This Item

Fórmula linear:
H2C=CHSO2CH3
Número CAS:
3680-02-2
Peso molecular:
106.14
Número CE:
222-958-0
Número MDL:
MFCD00007567
Código UNSPSC:
12352100
ID de substância PubChem:
24854858
NACRES:
NA.22

Ensaio

≥97%

Formulário

liquid

contém

0.02% p-tert-butylphenol as stabilizer

índice de refração

n20/D 1.463 (lit.)

p.e.

115-117 °C/19 mmHg (lit.)

densidade

1.212 g/mL at 25 °C (lit.)

grupo funcional

sulfone

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CS(=O)(=O)C=C

InChI

1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3

chave InChI

WUIJTQZXUURFQU-UHFFFAOYSA-N

Informações sobre genes

human ... LOC129293(129293)

Aplicação

Methyl vinyl sulfone has been used:
  • as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry[1]
  • in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric[2]
  • in Heck vinylation of aryl halides[3]

Pictogramas

Skull and crossbonesCorrosion
GHS06,GHS05

Palavra indicadora

Danger

Frases de perigo

H302,H310,H318

Classificações de perigo

Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

>235.4 °F - closed cup

Ponto de fulgor (°C)

> 113 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
MKCJ0797
MKCJ0798
MKCB7152
MKBT2643V
MKBJ9646V

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Butyl sulfone 99%

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Divinyl sulfone (stabilised) for synthesis

Sigma-Aldrich

8.21215

Divinyl sulfone

Gert Emmerechts et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 233-238 (2005-07-21)
A method is presented for improved detection of pseudouridine in nucleoside mixtures based on the specific derivatization with methyl vinyl sulfone followed by analysis by capillary HPLC-mass spectrometry. Reaction conditions were optimized in order to obtain the best yield and
G B Gordon et al.
Carcinogenesis, 12(12), 2393-2396 (1991-12-01)
The induction of quinone reductase [QR; NAD(P)H:(quinone acceptor) oxidoreductase; EC 1.6.99.2] in cultured cells and animal tissues of rodents has provided useful information on mechanisms of protection against carcinogens. We have developed a simple and efficient microtiter plate assay for
Synthesis, 3495-3495 (2006)
K L Dearfield et al.
Mutagenesis, 6(6), 519-525 (1991-11-01)
Over the past several years, we have been evaluating the mutagenicity and clastogenicity of compounds capable of Michael-type reactions. These compounds, including acrylamide, several acrylate and methacrylate esters, vinyl sulfones, and phorone, have been evaluated using TK+/- -3.7.2C mouse lymphoma
M D Shelby et al.
Mutation research, 250(1-2), 431-437 (1991-09-01)
Methyl vinyl sulfone and divinyl sulfone were tested for the induction of dominant lethal mutations and micronucleated bone-marrow erythrocytes in male mice. These chemicals were chosen for study because of their similarities in structure and chemical reactivity to acrylamide which
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