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224758

Sigma-Aldrich

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate

powder

Sinônimo(s):

Ru(BPY)3, Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate

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250 MG
R$ 433,00
1 G
R$ 1.276,00
5 G
R$ 4.174,00

R$ 433,00

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250 MG
R$ 433,00
1 G
R$ 1.276,00
5 G
R$ 4.174,00

About This Item

Fórmula empírica (Notação de Hill):
C30H24Cl2N6Ru · 6H2O
Número CAS:
50525-27-4
Peso molecular:
748.62
Número MDL:
MFCD00149670
Código UNSPSC:
12352103
ID de substância PubChem:
24853454
NACRES:
NA.23

R$ 433,00

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Formulário

powder

Nível de qualidade

100

adequação da reação

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

pf

>300 °C (lit.)

ativação do fotocatalisador

450 nm

cadeia de caracteres SMILES

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

chave InChI

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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Descrição geral

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.[1]

Aplicação

  • Used in the synthesis of hybrid catalysts which are used in oxidase based biosensors.[2]
  • Used as a luminophore for multiplexed signalling in bio analysis.[3]
  • Used in oxygen assesment in living cells.[4][5][6]
Learn More at the Professor and Product Portal of Professor Teshik Yoon and Professor Corey Stephenson.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
MKCV4811
MKCV8180
MKCT3761
MKCS6160
MKCT7773

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Stéphanie Heux et al.
Applied and environmental microbiology, 77(19), 7040-7049 (2011-08-16)
Miniaturization and high-throughput screening are currently the focus of emerging research areas such as systems biology and systems biotechnology. A fluorescence-based screening assay for the online monitoring of oxygen and pH and a numerical method to mine the resulting online
A Theoretical and Experimental Framework for Understanding Electrogenerated Chemiluminescence (ECL) Emission at Bipolar Electrodes
Mavre F, et al
Analytical Chemistry, 81, 6218-6225 (2009)
Attapulgite Clay Combined with Tris(2,2'bipyridyl)ruthenium(II) for the Enhancement of the
Electrogenerated Chemiluminescence Sensing
Gu B. et al
International Journal of Electrochemical Science, 7, 6202-6213 (2012)
Novel organic-inorganic hybrid material based on tris (2, 2'-bipyridyl) dichlororuthenium (II) hexahydrate and Dawson-type tungstophosphate K 7[H4PW18O62]? 18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam, M., & Easton, E. B.
Sensors and Actuators B, Chemical, 161(1), 520-527 (2012)
Old Molecules, New Concepts:[Ru (bpy) 3] 2+ as a Molecular Encoder-Decoder
Ceroni, P., Bergamini, G., & Balzani, V.
Angewandte Chemie (International Edition in English), 121(45), 8668-8670 (2009)
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Conteúdo relacionado

Stephenson Group – Professor Product Portal

Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

Yoon Group – Prof. Product Portal

Yoon lab exploits visible light photochemistry for unique chemical transformations.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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