222380

Allylpalladium(II) chloride dimer

98%

• Sinônimo(s): Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C₃H₅)]₂
• Fórmula empírica (Notação de Hill): C₆H₁₀Cl₂Pd₂
• Número CAS: 12012-95-2
• Peso molecular: 365.89
• Beilstein: 4124623
• Número CE: 234-579-8
• Número MDL: MFCD00044874
• Código UNSPSC: 12161600
• ID de substância PubChem: 24853328
• NACRES: NA.22

Propriedades

• Nível de qualidade: 200
• Ensaio: 98%
• forma: solid
• adequação da reação: core: palladium; reaction type: Cross Couplings; reagent type: catalyst; reaction type: C-H Activation
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoria alternativa mais ecológica: , Aligned
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
• chave InChI: TWKVUTXHANJYGH-UHFFFAOYSA-L

Descrição

Descrição geral

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Allylpalladium(II) chloride dimer has been employed for the following studies:

• Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
• Synthesis of N-heterocyclic carbene-palladium-η³-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
• Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
• As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315
• Declarações de precaução: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Classificações de perigo: Skin Irrit. 2
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Faceshields, Gloves