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Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

Sinônimo(s):

Iron(0) carbonyl, Pentacarbonyliron(0)

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About This Item

Fórmula linear:
Fe(CO)5
Número CAS:
13463-40-6
Peso molecular:
195.90
Número CE:
236-670-8
Número MDL:
MFCD00011001
Código UNSPSC:
12161600
ID de substância PubChem:
24851709
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

densidade de vapor

6.74 (vs air)

Nível de qualidade

100

pressão de vapor

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

temperatura de autoignição

122 °F

adequação da reação

core: iron
reagent type: catalyst

características do produto alternativo mais ecológico

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

índice de refração

n20/D 1.5196 (lit.)

p.e.

103 °C (lit.)

pf

−20 °C (lit.)

densidade

1.49 g/mL at 25 °C (lit.)

categoria alternativa mais ecológica

, Aligned

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

chave InChI

FYOFOKCECDGJBF-UHFFFAOYSA-N

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Categorias relacionadas

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Iron(0) pentacarbonyl can be used:
  • As an iron source to synthesize Fe-doped thin TiO2 films.[1]
  • As a ligand to synthesize complexes of gold(I) and Fe(CO)5,[2] silver and Fe(CO)5.[3]
Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

Pictogramas

FlameSkull and crossbones
GHS02,GHS06

Palavra indicadora

Danger

Frases de perigo

H225,H300 + H330,H311

Classificações de perigo

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

5.0 °F - closed cup

Ponto de fulgor (°C)

-15 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
SHBS5693
SHBS5688
SHBS3805
SHBS3804
SHBS3803

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Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

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Heterobimetallic Complexes Featuring Fe(CO)5 as a Ligand on Gold.
Wang G, et al.
Chemistry?A European Journal , 23(68), 17222-17226 (2017)
Plasma enhanced chemical vapor deposition of iron doped thin dioxide films, their structure and photowetting effect.
Sobczyk-Guzenda A, et al.
Thin Solid Films, 589, 605-612 (2015)
Heterobimetallic Silver-Iron Complexes Involving Fe(CO)5 Ligands
Wang G, et al.
Journal of the American Chemical Society, 139(40), 14292-14301 (2017)
Djordje Miljković et al.
Journal of neurochemistry, 118(2), 205-214 (2011-05-11)
Experimental autoimmune encephalomyelitis (EAE) is a model of multiple sclerosis. Dark Agouti rats immunized with spinal cord homogenate (SCH) and carbonyl iron (CI), as an adjuvant, develop severe hyperacute form of EAE. They succumb to EAE earlier and have higher
Lindsay Hewison et al.
Dalton transactions (Cambridge, England : 2003), 39(38), 8967-8975 (2010-08-18)
New CO-releasing molecules, CO-RMs, based on indenyl iron carbonyls have been identified. Half-lives for carbon monoxide (CO) release, (1)H NMR, (13)C NMR, IR, mass spectra, elemental analysis and biological data have been determined for the compounds. Limited correlations have been
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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. Qual è il grado di purezza?

    1 answer

    1. This product is not tested for purity and is considered a general use item. Should the purity and additional analytical testing be required, see product 481718. A link to this product page, as well as a sample Certificate of Analysis are provided below:

      481718 Iron(0) Pentacarbonyl product page:
      https://www.sigmaaldrich.com/US/en/product/aldrich/481718

      Sample Certificate of Analysis:
      https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/481718-BULKSHBQ5322.pdf

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