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125571

Sigma-Aldrich

5-Chloro-2-mercaptobenzothiazole

technical grade, ≥90%

Sinônimo(s):

5-Chloro-2-benzothiazolethiol, CMBT

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About This Item

Fórmula empírica (Notação de Hill):
C7H4ClNS2
Número CAS:
5331-91-9
Peso molecular:
201.70
Número CE:
226-235-0
Número MDL:
MFCD00005783
Código UNSPSC:
12352100
ID de substância PubChem:
24847675
NACRES:
NA.22

grau

technical grade

Ensaio

≥90%

pf

198-200 °C (lit.)

cadeia de caracteres SMILES

Sc1nc2cc(Cl)ccc2s1

InChI

1S/C7H4ClNS2/c8-4-1-2-6-5(3-4)9-7(10)11-6/h1-3H,(H,9,10)

chave InChI

NKYDKCVZNMNZCM-UHFFFAOYSA-N

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Descrição geral

5-Chloro-2-mercaptobenzothiazole(CMBZT) reacts with iodine in a molar ratio of 1:1 to form charge-transfer complex (CMBZT)I2.

Aplicação

5-Chloro-2-mercaptobenzothiazole (CMBZT) has been used in the analysis of lipopolysaccharide by negative-ion matrix-assisted laser desorption ionization-time of flight mass spectrometry. It has been used in the synthesis of the new mixed ligand silver(I) chloride complex with the heterocyclic thioamide CMBZT and tri(p-tolyl)phosphine. Found to be more sensitive than DHB for analysis of high mannose N-linked glycans. Used in analysis of peptidoglycan muropeptides.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

Certificados de análise (COA)

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αÁcido α-ciano-4-hidroxicinâmico matrix substance for MALDI-MS, ≥99.0% (HPLC)

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Norharmane crystalline

Sigma-Aldrich

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Adeline M Hajjar et al.
Infection and immunity, 74(12), 6730-6738 (2006-09-20)
Francisella tularensis is an intracellular gram-negative bacterium that is highly infectious and potentially lethal. Several subspecies exist of varying pathogenicity. Infection by only a few organisms is sufficient to cause disease depending on the model system. Lipopolysaccharide (LPS) of gram-negative
L Kyros et al.
Bioinorganic chemistry and applications, 386860-386860 (2010-04-10)
The synthesis and characterization of the silver(I) chloride complex of formula {[AgCI(CMBZT)(TPTP)(2)] . (MeOH)} (1) (CMBZT = 5-chloro-2-mercaptobenzothiazole, TPTP = tris(p-tolyl)phosphine) is described. Also the structure of the hydrate derivative {[AgCI(TPTP)(3)] . (0.5 . H(2)O)} (2) of the corresponding known
Natasha A Bencivenga-Barry et al.
Journal of bacteriology, 202(3) (2019-11-13)
Bacteroides is one of the most prominent genera in the human gut microbiome, and study of this bacterial group provides insights into gut microbial ecology and pathogenesis. In this report, we introduce a negative selection system for rapid and efficient
Synthesis and Characterization of (PTU) I2 (PTU= 6-n-propyl-2-thiouracil) and (CMBZT) I2 (CMBZT= 5-chloro-2-mercaptobenzothiazole) and Possible Implications for the Mechanism of Action of Anti-Thyroid Drugs.
Antoniadis CD, et al.
European Journal of Inorganic Chemistry, 2003(8), 1635-1640 (2003)
Ariadna Fernández-Calvet et al.
Scientific reports, 8(1), 6872-6872 (2018-05-04)
Airway infection by nontypeable Haemophilus influenzae (NTHi) associates to chronic obstructive pulmonary disease (COPD) exacerbation and asthma neutrophilic airway inflammation. Lipids are key inflammatory mediators in these disease conditions and consequently, NTHi may encounter free fatty acids during airway persistence.
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