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223425

Sigma-Aldrich

Kaliumoxalat Monohydrat

ACS reagent, 99%

Synonym(e):

Ethandisäure Kaliumsalz, Oxalsäure Kaliumsalz

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About This Item

Lineare Formel:
(COOK)2 · H2O
CAS-Nummer:
Molekulargewicht:
184.23
Beilstein:
3752576
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.21
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Qualität

ACS reagent

Qualitätsniveau

Beschreibung

neutrality passes test

Assay

98.5-101.0% (ACS specification)
99%

Form

crystals or chunks

Verunreinigungen

H2SO4, passes test (darkened)
≤0.01% insolubles

pH-Wert

7.0-8.5 (25 °C, 50 g/L)

Löslichkeit

H2O: 10%

Anionenspuren

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.01%

Kationenspuren

Fe: ≤0.001%
NH4+: ≤0.002%
Na: ≤0.02%
heavy metals: ≤0.002% (by ICP)

SMILES String

O.[K+].[K+].[O-]C(=O)C([O-])=O

InChI

1S/C2H2O4.2K.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);;;1H2/q;2*+1;/p-2

InChIKey

QCPTVXCMROGZOL-UHFFFAOYSA-L

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Allgemeine Beschreibung

Potassium oxalate monohydrate (POM) is a potassium salt of oxalic acid. Its crystal structure has been investigated by three-dimensional neutron diffraction studies.[1]

Anwendung

Potassium oxalate monohydrate may be used in the preparation of SBA-15 (Santa Barbara Amoprhous-15)- catalyst.[2]
Potassium oxalate monohydrate may be used in the synthesis of bis(2,2"-bipyridine) (oxalato-O,O′)nickel(ii) tetrahydrate, a mononuclear mixed-ligand complex.[3]

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Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 1


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Die Dokumentenbibliothek aufrufen

EPR and optical absorption studies of vanadyl ions in potassium oxalate monohydrate.
Kripal R, et al.
Physica B: Condensed Matter (Amsterdam, Netherlands), 392(1), 281-287 (2007)
Solid-state chemistry of nickel (II)-oxalate-amine systems. Synthesis, characterization and crystal structure of the bis (2, 2'-bipyridine)(oxalato-O, O') nickel (II) tetrahydrate.
Roman P, et al.
Polyhedron, 14(20), 2863-2869 null
The influence of water on the dispersion of vanadia supported on silica SBA-15: A combined XPS and Raman study.
Hess C, et al.
The Journal of Physical Chemistry C, 111(26), 9471-9479 (2007)
Neutron diffraction refinement of the structure of potassium oxalate monohydrate.
Sequeira A, et al.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 26(1), 77-80 (1970)
L Sosvorová et al.
Physiological research, 63(4), 521-527 (2014-06-09)
Increased homocysteine levels in serum are typical features of neurodegenerative brain diseases including hydrocephalus. The most frequent therapeutic approach consists of the insertion of a shunt, connecting the brain ventricles to an alternative drainage site. To decide whether the patient

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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